Synthesis and surface chemistry of high quality wurtzite and kesterite Cu2ZnSnS4 nanocrystals using tin(II) 2-ethylhexanoate as a new tin source

被引：22

作者：

Gabka, Grzegorz ^{[1
]}

Bujak, Piotr ^{[1
]}

Gryszel, Maciej ^{[1
]}

Ostrowski, Andrzej ^{[1
]}

Malinowska, Karolina ^{[2
]}

Zukowska, Grazyna Z. ^{[1
]}

Agnese, Fabio ^{[3
,4
]}

Pron, Adam ^{[1
]}

Reiss, Peter ^{[3
,5
,6
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

[2] Univ Warsaw, Fac Chem, PL-02093 Warsaw, Poland

[3] Univ Grenoble Alpes, F-38000 Grenoble, France

[4] CEA INAC SP2M, Lab Etud Mat Microscopie Avancee, Grenoble, France

[5] CEA INAC SPrAM, Lab Elect Mol Organ & Hybrid, F-38054 Grenoble 9, France

[6] CNRS UMR5819 SPrAM, F-38000 Grenoble, France

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 65期

关键词：

SULFIDE NANOCRYSTALS; SOLAR-CELLS; NANOPARTICLES; MECHANISM; ZN;

D O I：

10.1039/c5cc04151a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel synthesis method for the preparation of Cu2ZnSnS4 nanocrystals is presented using a liquid precursor of tin, namely tin(II) 2-ethylhexanoate, which yields small and nearly monodisperse NCs either in the kesterite or in the wurtzite phase depending on the sulfur source (elemental sulfur in oleylamine vs. dodecanethiol).

引用

页码：12985 / 12988

页数：4

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