Quantifying the influence of calcium ion concentration on the corrosion of high-purity magnesium, AZ91, WE43 in modified Hanks' solutions

被引:5
|
作者
Py, Baptiste [1 ,2 ]
Johnston, Sean [1 ]
Hardy, Alexander [1 ]
Shi, Zhiming [1 ]
Wolski, Krzysztof [2 ]
Atrens, Andrej [1 ]
机构
[1] Univ Queensland, Mat Engn, Sch Mech & Min Engn, Brisbane, Qld 4072, Australia
[2] Ecole Natl Super Mines, Mat Engn, Engn Sch, F-42100 St Etienne, France
基金
澳大利亚研究理事会;
关键词
in vitrocorrosion; calcium ions; magnesium; weight loss; simulated body fluid; IN-VIVO CORROSION; MG CORROSION; VITRO CORROSION; ALLOYS; ZE41; PERFORMANCE; BEHAVIOR; POLARIZATION; BIOCORROSION; MG2ZN0.2MN;
D O I
10.1088/2053-1591/abb1f4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion rate in a modified Hanks' solution (containing no Ca(2+)ions) was higher than in Hanks' solution. The increase was by a factor of similar to 12 for HP Mg and AZ91, and a factor of similar to 6 for WE43. This quantitatively highlights the critical role of Ca(2+)ions for Mg corrosion in synthetic body fluids. The Ca(2+)ion containing solutions produced a dense corrosion-product layer of hydroxyapatite, Ca-3(PO4)(2)) Ca(OH)(2), a greater fraction of which stayed on the corroding surface (similar to 0.2-0.3) compared with the Ca(2+)ion free solutions which produced magnesium phosphate, Mg-3(PO4)(2).
引用
收藏
页数:13
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