Cross-sections of bound-free I2(0g+, 1g(aa, ab) ←hvf B0u+, vB=18-21) and bound-bound I2(0g+, 1u(bb) ←hvf B0u+, vB=21, JB) transitions at a fundamental harmonic of the Nd:YAG laser

被引:4
作者
Akopyan, M. E. [1 ]
Baturo, V. V. [1 ]
Lukashov, S. S. [1 ]
Poretsky, S. A. [1 ]
Pravilov, A. M. [1 ]
Teschmit, N. [2 ]
机构
[1] St Petersburg State Univ, Fac Phys, VA Fock Inst Phys, St Petersburg 198504, Russia
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Phys & Theoret Chem, Braunschweig, Germany
关键词
cross-sections; allowed transitions; forbidden transitions; ION-PAIR STATES; FOURIER-TRANSFORM SPECTROSCOPY; DIPOLE-MOMENT FUNCTIONS; VALENCE STATES; OPTICAL POPULATION; MOLECULAR-IODINE; ABSORPTION-SPECTRUM; DISSOCIATION LIMIT; VDW COMPLEXES; I-2;
D O I
10.1088/0953-4075/47/5/055101
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Bound-free electric dipole allowed I-2(a1(g), a' 0(g)(+)(aa), 0(g)(+), c1(g), c' 1(g)(ab) <- hv(f)(i) B0(u)(+), v(B) = 18 - 21, J(B)) and bound-bound electric dipole allowed I-2(0(g)(+) (bb) <- hv(f)(i) B0(u)(+), v(B), J(B)) and electric dipole forbidden I-2(1(u)(bb) <- hv(f)(i) B0(u)(+), v(B), J(B)) transitions at a fundamental harmonic of the Nd: YAG laser, h. i f, have been studied. Excitation spectra of the I-2 (B, v(B), J(B) -> X, v(X) = 1, J(X)) luminescence from the B, v(B) = 18, 20, 21, J(B) rovibronic states have been measured with switched on and switched off h. i f generation. Temporal behaviors of the luminescence intensities from these states with switched on and switched off hv(f)(i) generation have also been measured. These data allow us to determine or estimate cross-sections of the electric dipole allowed and electric dipole forbidden transitions under study. Dipole moment of the I-2(0(g)(+) (bb), v(0) = 7 <- hv(f)(i) B0(u)(+), v(B), J(B)) transition has also been determined.
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页数:9
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