Bifunctional LaxNdyGdzSc4-x-y-z(BO3)4 crystal: Czochralski growth, linear and nonlinear optical properties, and near-infrared laser emission performances

被引:10
作者
Greculeasa, Madalin [1 ,2 ]
Broasca, Alin [1 ,2 ]
Voicu, Flavius [1 ]
Hau, Stefania [1 ]
Croitoru, Gabriela [1 ]
Stanciu, George [1 ]
Gheorghe, Cristina [1 ]
Pavel, Nicolaie [1 ]
Gheorghe, Lucian [1 ]
机构
[1] Natl Inst Laser Plasma & Radiat Phys, Lab Solid State Quantum Elect, Magurele 077125, Romania
[2] Univ Bucharest, Doctoral Sch Phys, Bucharest, Romania
关键词
Czochralski; Neodymium; Spectroscopy; Nonlinear optical crystal; Laser crystal; Bifunctional crystal; ND3+;
D O I
10.1016/j.optlastec.2020.106433
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
High optical quality LaxNdyGdzSc4-x-y-z(BO3)(4) (Nd:LGSB) single crystal has been obtained by the Czochralski technique. The crystal composition was found to be La0.721Nd0.046Gd0.452Sc2.781(BO3)(4). Low-temperature spectroscopic investigations revealed that the Nd3+ ions enter only in La3+ ions sites. The main nonlinear optical (NLO) properties of Nd:LGSB (4.6 at.%) crystal were found to be comparable to those of yttrium aluminum borate (YAB) crystal. Laser emission at 1.06 mu m with 24.5 mJ energy per pulse for 35.6 mJ absorbed pump pulse energy at 807 nm and 0.71 slope efficiency has been obtained from a c-cut Nd:LGSB (4.6 at.%) uncoated crystal sample with 6.14 mm length. Slope efficiency as high as 0.73 was obtained from an uncoated 2.96 mm thick acut sample. The good NLO properties of Nd:LGSB crystal together with the excellent near-infrared laser performances, recommends Nd:LGSB as a very promising bifunctional crystal in self-frequency doubling configuration.
引用
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页数:8
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