Collisional quantum interference on rotational energy transfer in Na2 (A1Σu+, ν=8 ∼ b3Π0u, ν=14)-Na system

被引:9
作者
Sun, MT [1 ]
Wang, WL
Song, P
Ma, FC
机构
[1] Liaoning Univ, Dept Phys, Shenyang 110036, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Lab 2, State Key Mol React Dynam, Dalian 116023, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.cplett.2004.01.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Collisional quantum interference (CQI) on rotational energy transfer was observed in Na-2 (A(1) Sigma(u)(+) , upsilon = 8 similar to b(3)Pi(0u), upsilon = 14) system in collision with Na, but the interference angle was not measured out due to the lack of enough experimental data. As a complementarity of the experiment, the interference angle is calculated theoretically in this Letter, based on the time-dependent first order Born approximation, and taking into account the anisotropic Lernnard-Jones interaction potentials. The calculated value gives a quantitative and accurate description of CQI. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:430 / 436
页数:7
相关论文
共 35 条
[4]   SYMMETRY SELECTION-RULES IN INELASTIC-COLLISIONS OF DIATOMIC-MOLECULES IN 3-PI ELECTRONIC STATES [J].
ALEXANDER, MH ;
POUILLY, B .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (03) :1545-1546
[5]   STATE-TO-STATE ROTATIONAL PHASE COHERENCE EFFECT ON THE VIBRATION-ROTATION BAND SHAPE - AN ACCURATE QUANTUM CALCULATION FOR CO-HE [J].
BOISSOLES, J ;
BOULET, C ;
ROBERT, D ;
GREEN, S .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (10) :5392-5398
[6]   LABELING OF PARITY DOUBLET LEVELS IN LINEAR MOLECULES [J].
BROWN, JM ;
HOUGEN, JT ;
HUBER, KP ;
JOHNS, JWC ;
KOPP, I ;
LEFEBVREBRION, H ;
MERER, AJ ;
RAMSAY, DA ;
ROSTAS, J ;
ZARE, RN .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1975, 55 (1-3) :500-503
[7]   Laboratory conditions in the coherent control of reactive scattering [J].
Brumer, P ;
Abrashkevich, A ;
Shapiro, M .
FARADAY DISCUSSIONS, 1999, 113 :291-302
[8]   Further study on collisional quantum interference effect in energy transfer within CO singlet-triplet mixed states [J].
Chen, XL ;
Sha, GH ;
Jiang, B ;
He, JB ;
Zhang, CH .
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (19) :8661-8665
[9]   Quantum interference effect on collisional energy transfer within singlet ∼ triplet mixed states of Na2 A 1Σu+(v = 8) ∼ b 3Π0u(v=14) [J].
Chen, XL ;
Chen, HM ;
Li, J ;
Liu, YM ;
Dai, XC ;
Sha, GH ;
Xie, JC ;
Zhang, CH ;
Li, L .
CHEMICAL PHYSICS LETTERS, 2000, 318 (1-3) :107-112
[10]   Interference of quantized transition-state pathways in the H+D2→D+HD chemical reaction [J].
Dai, DX ;
Wang, CC ;
Harich, SA ;
Wang, XY ;
Yang, XM ;
Chao, SD ;
Skodje, RT .
SCIENCE, 2003, 300 (5626) :1730-1734