In Vitro Degradation of Absorbable Zinc Alloys in Artificial Urine

被引:36
作者
Champagne, Sebastien [1 ,2 ]
Mostaed, Ehsan [3 ]
Safizadeh, Fariba [1 ]
Ghali, Edward [1 ]
Vedani, Maurizio [3 ]
Hermawan, Hendra [1 ,2 ]
机构
[1] Laval Univ, Dept Min Met & Mat Engn, 1065 Ave Med, Quebec City, PQ G1V 0A6, Canada
[2] CHU Quebec, Res Ctr, 10 Rue Espinay, Quebec City, PQ G1L 3L5, Canada
[3] Politecn Milan, Dept Mech Engn, Via La Masa 1, I-20156 Milan, Italy
基金
加拿大自然科学与工程研究理事会;
关键词
absorbable; corrosion; degradation; magnesium; ureteral stent; zinc; MAGNESIUM ALLOYS; CORROSION BEHAVIOR; TENSILE-STRENGTH; URETERAL STENTS; VIVO CORROSION; FILM; RESISTANCE; IMPLANT; XPS; CONVERSION;
D O I
10.3390/ma12020295
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Absorbable metals have potential for making in-demand rigid temporary stents for the treatment of urinary tract obstruction, where polymers have reached their limits. In this work, in vitro degradation behavior of absorbable zinc alloys in artificial urine was studied using electrochemical methods and advanced surface characterization techniques with a comparison to a magnesium alloy. The results showed that pure zinc and its alloys (Zn-0.5Mg, Zn-1Mg, Zn-0.5Al) exhibited slower corrosion than pure magnesium and an Mg-2Zn-1Mn alloy. The corrosion layer was composed mostly of hydroxide, carbonate, and phosphate, without calcium content for the zinc group. Among all tested metals, the Zn-0.5Al alloy exhibited a uniform corrosion layer with low affinity with the ions in artificial urine.
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页数:13
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