Directional Self-Assembly of a Colloidal Metal-Organic Framework

被引：120
|
作者：
Yanai, Nobuhiro [1 ]
Granick, Steve [1 ,2 ]
机构：
[1] Univ Illinois, Dept Chem, Dept Mat Sci & Engn, Urbana, IL 61801 USA
[2] Univ Illinois, Dept Phys, Urbana, IL 61801 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 23期
关键词：
colloids; crystals; metal-organic frameworks; self-assembly; surface chemistry; IMIDAZOLATE; NANOCRYSTALS; CRYSTALLINE;
D O I：
10.1002/anie.201109132
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
MOFs get attraction: Supraparticle self-assembly of a colloidal metal-organic framework (MOF) is achieved through simple capillary and van der Waals attractions. When suspensions of MOF particles are allowed to evaporate, hexagonal packings with controlled crystal orientation result (see scheme). The self-assembly can be visualized at the single-particle level. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5638 / 5641
页数：4
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