An ordered, extra-large mesoporous ceramic acid with strong Bronsted acid sites and excellent thermal/hydrothermal stability

被引:8
作者
Chen, Changlei [1 ]
Li, Sha [1 ]
Xu, Shaodan [1 ]
Lou, Hui [1 ]
Xiao, Liping [1 ]
Fan, Jie [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310027, Zhejiang, Peoples R China
基金
美国国家科学基金会;
关键词
HYDROTHERMAL STABILITY; CATALYTIC-ACTIVITY; MOLECULAR-SIEVES; PORE DIAMETERS; SILICA; MCM-41; ALUMINOSILICATES; SBA-15; TRANSESTERIFICATION; ZIRCONIA;
D O I
10.1039/c4cc00222a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A thermal and hydrothermal stable mesoporous ceramic acid (mCA) was synthesized by uniform coating of a WZrOx layer onto the internal surface of extra-large mesoporous silica (EP-FDU-12). Its ordered mesoporous structure and strong Bronsted acid sites display excellent thermal (1000 degrees C, air, 5 h) and hydrothermal (water steam, 300 degrees C, 24 h) stability.
引用
收藏
页码:3457 / 3459
页数:3
相关论文
共 33 条
[1]   Single-step preparation and catalytic activity of mesoporous MCM-41 and SBA-15 silicas functionalized with perfluoroalkylsulfonic acid groups analogous to Nafion® [J].
Alvaro, M ;
Corma, A ;
Das, D ;
Fornés, V ;
García, H .
CHEMICAL COMMUNICATIONS, 2004, (08) :956-957
[2]   Transesterification of ethylacetoacetate catalysed by metal free mesoporous carbon nitride [J].
Anand, Chokkalingam ;
Priya, Subramaniam Vishnu ;
Lawrence, Geoffrey ;
Mane, Gurudas P. ;
Dhawale, Dattatray S. ;
Prasad, Kumaresapillai S. ;
Balasubramanian, Veerappan V. ;
Wahab, Mohammad A. ;
Vinu, Ajayan .
CATALYSIS TODAY, 2013, 204 :164-169
[3]   Cage type mesoporous ferrosilicate catalysts with 3D structure for benzylation of aromatics [J].
Anand, Chokkalingam ;
Priya, Subramaniam Vishnu ;
Lawrence, Geoffrey ;
Dhawale, Dattatray S. ;
Varghese, Shaji ;
Wahab, Mohammad A. ;
Prasad, Kumaravel S. ;
Vinu, Ajayan .
CATALYSIS TODAY, 2013, 204 :125-131
[4]   Preparation of mesoporous titanosilicate molecular sieves with a cage type 3D porous structure for cyclohexene epoxidation [J].
Anand, Chokkalingam ;
Srinivasu, Pavuluri ;
Mane, Gurudas P. ;
Talapaneni, Siddulu N. ;
Dhawale, Dattatray S. ;
Wahab, Mohammad A. ;
Priya, Subramaniam Vishnu ;
Varghese, Shaji ;
Sugi, Yoshihiro ;
Vinu, Ajayan .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 160 :159-166
[5]   Cracking behavior of asphaltene in the presence of iron catalysts supported on mesoporous molecular sieve with different pore diameters [J].
Byambajav, E ;
Ohtsuka, Y .
FUEL, 2003, 82 (13) :1571-1577
[6]   A detailed study of thermal, hydrothermal, and mechanical stabilities of a wide range of surfactant assembled mesoporous silicas [J].
Cassiers, K ;
Linssen, T ;
Mathieu, M ;
Benjelloun, M ;
Schrijnemakers, K ;
Van Der Voort, P ;
Cool, P ;
Vansant, EF .
CHEMISTRY OF MATERIALS, 2002, 14 (05) :2317-2324
[7]   STUDIES ON MESOPOROUS MATERIALS .1. SYNTHESIS AND CHARACTERIZATION OF MCM-41 [J].
CHEN, CY ;
LI, HX ;
DAVIS, ME .
MICROPOROUS MATERIALS, 1993, 2 (01) :17-26
[8]   ACIDITY AND STABILITY OF MCM-41 CRYSTALLINE ALUMINOSILICATES [J].
CORMA, A ;
FORNES, V ;
NAVARRO, MT ;
PEREZPARIENTE, J .
JOURNAL OF CATALYSIS, 1994, 148 (02) :569-574
[9]   Synthesis, characterization and catalytic activity of MCM-41-type mesoporous silicas functionalized with sulfonic acid [J].
Díaz, I ;
Mohino, F ;
Pérez-Pariente, J ;
Sastre, E .
APPLIED CATALYSIS A-GENERAL, 2001, 205 (1-2) :19-30
[10]   Thermal and mechanical stability of micelle-templated silica supports for catalysis [J].
Galarneau, A ;
Desplantier-Giscard, D ;
Di Renzo, F ;
Fajula, F .
CATALYSIS TODAY, 2001, 68 (1-3) :191-200