Competitive Si and La effect in HfO2 phase stabilization in multi-layer (La2O3)0.08(HfO2) films

被引:8
作者
Cao, Duo [1 ]
Cheng, Xinhong [1 ]
Yu, Yuehui [1 ]
Li, Xiaolong [2 ]
Liu, Chunze [2 ]
Shen, Dashen [3 ]
Maendl, Stephan [4 ]
机构
[1] Chinese Acad Sci, SIMIT, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China
[2] Shanghai Synchrotron Radiat Facil, Shanghai 200061, Peoples R China
[3] Univ Alabama, Huntsville, AL 35899 USA
[4] Leibniz Inst Oberflachenmodifizierung, D-04318 Leipzig, Germany
关键词
ZRO2;
D O I
10.1063/1.4819198
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effect of Si diffusion in HfO2 and the presence of La on phase transformation were investigated. Tetragonal HfO2 structures exhibited high permittivity, and the addition of exotic atoms to HfO2 facilitated tetragonal phase transformation. In multi-layer (La2O3)(0.08)(HfO2) films, the top HfO2 layer was transformed into a perfect tetragonal structure, and the bottom HfO2 layer near the interfacial layer was of a cubic structure, after annealing at 800 degrees C. The permittivity reached 50-60. Si diffusion into the HfO2 film stabilized the tetragonal structure, and La incorporation into HfO2 facilitated the transition of the cubic structure. (C) 2013 AIP Publishing LLC.
引用
收藏
页数:4
相关论文
共 12 条
[1]   Mechanism of the monoclinic-to-tetragonal phase transition induced in zirconia and hafnia by swift heavy ions [J].
Benyagoub, A .
PHYSICAL REVIEW B, 2005, 72 (09)
[2]   Cubic-Structured HfO2 With Optimized Doping of Lanthanum for Higher Dielectric Constant [J].
He, Wei ;
Zhang, Lu ;
Chan, Daniel S. H. ;
Cho, Byung Jin .
IEEE ELECTRON DEVICE LETTERS, 2009, 30 (06) :623-625
[3]   Initial phases in sputter deposited HfO2-Al2O3 nanolaminate films [J].
Hoppe, E. E. ;
Aita, C. R. ;
Gajdardziska-Josifovska, M. .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[4]   O3-based atomic layer deposition of hexagonal La2O3 films on Si(100) and Ge(100) substrates [J].
Lamagna, L. ;
Wiemer, C. ;
Perego, M. ;
Volkos, S. N. ;
Baldovino, S. ;
Tsoutsou, D. ;
Schamm-Chardon, S. ;
Coulon, P. E. ;
Fanciulli, M. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (08)
[5]   First-principles study on doping and phase stability of HfO2 [J].
Lee, Choong-Ki ;
Cho, Eunae ;
Lee, Hyo-Sug ;
Hwang, Cheol Seong ;
Han, Seungwu .
PHYSICAL REVIEW B, 2008, 78 (01)
[6]   Atomic mechanism of electric dipole formed at high-K: SiO2 interface [J].
Lin, L. ;
Robertson, J. .
JOURNAL OF APPLIED PHYSICS, 2011, 109 (09)
[7]   Maximizing performance for higher K gate dielectrics [J].
Robertson, John .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (12)
[8]   Crystallized HfLaO embedded tetragonal ZrO2 for dynamic random access memory capacitor dielectrics [J].
Shin, Yunsang ;
Min, Kyung Kyu ;
Lee, Seok-Hee ;
Lim, Sung Kyu ;
Oh, Jae Sub ;
Lee, Kee-Jeung ;
Hong, Kwon ;
Cho, Byung Jin .
APPLIED PHYSICS LETTERS, 2011, 98 (17)
[9]   Dielectric constant enhancement due to Si incorporation into HfO2 [J].
Tomida, Kazuyuki ;
Kita, Koji ;
Toriumi, Akira .
APPLIED PHYSICS LETTERS, 2006, 89 (14)
[10]   Structural and dielectric properties of crystalline and amorphous ZrO2 [J].
Vanderbilt, D ;
Zhao, XY ;
Ceresoli, D .
THIN SOLID FILMS, 2005, 486 (1-2) :125-128