Assembly of a Two-Fold Interpenetrated Three-Dimensional Metal-Organic Framework by Using the Template Function of Keggin Anions

被引：3
|
作者：
Zhou, Shi [1 ,2 ]
Chen, Ya-Guang [3 ]
Liu, Bo [1 ,2 ]
Xu, Yan-Hong [1 ,2 ]
Wang, Xiu-Yan [1 ,2 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Jilin, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
[3] Northeast Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalates Sci, Changchun 130024, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2018年 / 29卷 / 03期
关键词：
Polyoxometalates; Interpenetration; Metal-organic framework; POM template; Crystal structure; Photocatalysis; COORDINATION POLYMER; BUILDING-BLOCKS; NETWORK; POLYOXOMETALATE; OXIDATIONS; TOPOLOGY;
D O I：
10.1007/s10876-018-1347-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A metal-organic framework [Co-2(btp)(3)(GeMo12O40)] (1) (btp = 1,3-bis-(1,2,4-triazol-1-yl)propane) has been constructed by using the template function of the Keggin anions GeMo12O40 (4-). Single-crystal X-ray analysis reveals that the structure exhibits two-fold interpenetrated 3D host metal-organic framework constructed from cobalt(II) and btp linkers and the voids of which are occupied by Keggin anions. The optical band gap of 1 indicates that it is potential wide-gap semiconductive material. The photocatalytic activity of compound 1 in degradation of MB under visible light and UV light irradiation are also investigated.
引用
收藏
页码：417 / 423
页数：7
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