Synthesis of calix[4]arene derivatives with NLO properties

被引：4

作者：

Bai, Z ^{[1
]}

Zhang, CZ ^{[1
]}

Lu, GY ^{[1
]}

Liu, F ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Dept Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2006年 / 24卷 / 01期

关键词：

chromophore; calixarene; nonlinear optics; conformation; Knoevenagel condensation;

D O I：

10.1002/cjoc.200690006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new chromophore compounds with NLO properties were prepared by Knoevenagel condensation from formyl or diformyl calix[4]arene and isophorone derivatives in the presence of piperidine and acetic acid, respectively. In these chromophore calix[4]arenes, the ring locked trienes were employed as the conjugation bridge and electron acceptor in D-pi-A units. The NMR spectra demonstrated that they existed in a cone conformation and consequently non-conjugated D-pi-A units could be oriented at nearly the same direction.

引用

页码：124 / 128

页数：5

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