Isotropic and Anisotropic Growth of Metal-Organic Framework (MOF) on MOF: Logical Inference on MOF Structure Based on Growth Behavior and Morphological Feature
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作者:
Choi, Sora
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Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South KoreaYonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
Choi, Sora
[1
]
Kim, Taeho
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Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South KoreaYonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
Kim, Taeho
[1
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Ji, Hoyeon
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Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South KoreaYonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
Ji, Hoyeon
[1
]
Lee, Hee Jung
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Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South KoreaYonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
Lee, Hee Jung
[1
]
Oh, Moonhyun
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Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South KoreaYonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
Oh, Moonhyun
[1
]
机构:
[1] Yonsei Univ, Dept Chem, 50 Yonsei Ro, Seoul 120749, South Korea
The growth of one metal organic framework (MOP) on another MOF for constructing a heterocompositional hybrid MOF is an interesting research topic because of the curiosity regarding the occurrence of this phenomenon and the value-of hybrid MOFs as multifunctional materials or routes for fine-tuning MOF properties. In particular, the anisotropic growth of MOF on MOF is fascinating for the development of MOFs possessing atypical shapes and heterostructures or abnormal properties. Herein, we clarify the understanding of growth behavior of a secondary MOF on an initial MOF template, such as isotropic or anisotropic ways associated with their cell parameters. The isotropic growth of MIL-68-Br on: the MIL-68 template results in the formation of core shell-type MIL-68@MIL-68-Br. the unique anisotropic growth of a secondary MOF (MOF-NDC) on the MIL-68 template results in semitubular particles, and structural features of this unknown secondary MOF are successfully speculated for the first time on the basis of its unique growth behavior and morphological characteristics. Finally, the validation of this structural speculation is verified by the powder X-ray diffraction, and the selected area electron diffraction studies. The results suggests that the growth-behavior and morphological features of MOFs should be considered to be important factors for understanding the MOFs' structures.
机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Chen, Banglin
;
Wang, Liangbo
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Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Wang, Liangbo
;
Xiao, Yunqing
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Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Xiao, Yunqing
;
Fronczek, Frank R.
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Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Fronczek, Frank R.
;
Xue, Ming
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Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Xue, Ming
;
Cui, Yuanjing
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Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Cui, Yuanjing
;
Qian, Guodong
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Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Chen, Banglin
;
Wang, Liangbo
论文数: 0引用数: 0
h-index: 0
机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Wang, Liangbo
;
Xiao, Yunqing
论文数: 0引用数: 0
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机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Xiao, Yunqing
;
Fronczek, Frank R.
论文数: 0引用数: 0
h-index: 0
机构:
Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Fronczek, Frank R.
;
Xue, Ming
论文数: 0引用数: 0
h-index: 0
机构:
Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USAZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Xue, Ming
;
Cui, Yuanjing
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机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
Cui, Yuanjing
;
Qian, Guodong
论文数: 0引用数: 0
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机构:
Zhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R ChinaZhejiang Univ, State Key Lab Silicon Mat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China