Fluorous Metal-Organic Frameworks with Enhanced Stability and High H2/CO2 Storage Capacities

被引：134
作者：
Zhang, Da-Shuai [1 ,2 ]
Chang, Ze [1 ,2 ]
Li, Yi-Fan [3 ]
Jiang, Zhong-Yi [3 ]
Xuan, Zhi-Hong [1 ,2 ]
Zhang, Ying-Hui [1 ,2 ]
Li, Jian-Rong [4 ]
Chen, Qiang [1 ,2 ]
Hu, Tong-Liang [1 ,2 ]
Bu, Xian-He [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[2] Nankai Univ, Tianjin Key Lab Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
[3] Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
[4] Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
来源：
SCIENTIFIC REPORTS | 2013年 / 3卷
关键词：
ULTRAHIGH SURFACE-AREA; GAS-ADSORPTION; HYDROGEN ADSORPTION; FUNCTIONAL-GROUPS; HIGH-DENSITY; SEPARATION; POLYMER; POROSITY; CO2; CU-3(BTC)(2);
D O I：
10.1038/srep03312
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A new class of metal-organic frameworks (MOFs) has been synthesized by ligand-functionalization strategy. Systematic studies of their adsorption properties were performed at low and high pressure. Importantly, when fluorine was introduced into the framework via the functionalization, both the framework stabilities and adsorption capacities towards H-2/CO2 were enhanced significantly. This consequence can be well interpreted by theoretical studies of these MOFs structures. In addition, one of these MOFs TKL-107 was used to fabricate mixed matrix membranes, which exhibit great potential for the application of CO2 separation.
引用
收藏
页数：7
相关论文
共 53 条
[1]  
Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO
[2]  
2-3
[3]   High and Selective CO2 Uptake in a Cobalt Adeninate Metal-Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores [J].
An, Jihyun ;
Geib, Steven J. ;
Rosi, Nathaniel L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (01) :38-+
[4]   Membrane Gas Separation: A Review/State of the Art [J].
Bernardo, P. ;
Drioli, E. ;
Golemme, G. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (10) :4638-4663
[5]   Gas permeation parameters of mixed matrix membranes based on the polymer of intrinsic microporosity PIM-1 and the zeolitic imidazolate framework ZIF-8 [J].
Bushell, Alexandra F. ;
Attfield, Martin P. ;
Mason, Christopher R. ;
Budd, Peter M. ;
Yampolskii, Yuri ;
Starannikova, Ludmila ;
Rebrov, Alexander ;
Bazzarelli, Fabio ;
Bernardo, Paola ;
Jansen, Johannes Carolus ;
Lanc, Marek ;
Friess, Karel ;
Shantarovich, Victor ;
Gustov, Vadim ;
Isaeva, Vera .
JOURNAL OF MEMBRANE SCIENCE, 2013, 427 :48-62
[6]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[7]   Rational Construction of 3D Pillared Metal-Organic Frameworks: Synthesis, Structures, and Hydrogen Adsorption Properties [J].
Chang, Ze ;
Zhang, Da-Shuai ;
Chen, Qiang ;
Li, Rui-Fang ;
Hu, Tong-Liang ;
Bu, Xian-He .
INORGANIC CHEMISTRY, 2011, 50 (16) :7555-7562
[8]   Synthesis, structure and properties of microporous metal-organic frameworks constructed from Ni(II)/Cd(II), Tpt and H4bpta [J].
Chang, Ze ;
Zhang, Da-Shuai ;
Hu, Tong-Liang ;
Bu, Xian-He .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (07) :1082-1085
[9]   Microporous Metal-Organic Framework Based on Supermolecular Building Blocks (SBBs): Structure Analysis and Selective Gas Adsorption Properties [J].
Chang, Ze ;
Zhang, Da-Shuai ;
Hu, Tong-Liang ;
Bu, Xian-He .
CRYSTAL GROWTH & DESIGN, 2011, 11 (06) :2050-2053
[10]   Luminescent Functional Metal-Organic Frameworks [J].
Cui, Yuanjing ;
Yue, Yanfeng ;
Qian, Guodong ;
Chen, Banglin .
CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162
123456