Hydrothermal synthesis of WO3 nanoplates as highly sensitive cyclohexene sensor and high-efficiency MB photocatalyst

被引:58
作者
Gao, Xiaoqing [1 ]
Su, Xintai [1 ]
Yang, Chao [1 ]
Xiao, Feng [1 ]
Wang, Jide [1 ]
Cao, Xudong [2 ]
Wang, Shoujiang [2 ]
Zhang, Lu [2 ]
机构
[1] Xinjiang Univ, Coll Chem & Chem Engn, Minist Key Lab Oil & Gas Fine Chem, Urumqi 830046, Peoples R China
[2] Fire Dept Xinjiang Uygur Autonomous Reg, Urumqi 830063, Peoples R China
关键词
Tungsten oxides; Nanoplates; Cyclohexene; Gas sensors; Photocatalyst; GAS-SENSING PROPERTIES; TUNGSTEN-OXIDE; THIN-FILMS; IN-SITU; NANORODS; PHOTOLUMINESCENCE; NANOPARTICLES; NANOCRYSTALS; POLYPYRROLE; FABRICATION;
D O I
10.1016/j.snb.2013.02.031
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper, triclinic WO3 nanoplates with prominent cyclohexene sensing and photocatalytic properties were fabricated via a facile hydrothermal method assisted with p-aminobenzoic acid. The as-prepared product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). XRD, SEM and TEM images illustrated that the WO3 nanoplates have a triclinic phase with the length of 100-200 nm and the thickness of 50-80 nm. The gas sensing properties of the WO3 nanoplates were measured by detection of methanol, ethanol, cyclohexane, benzene, ethyl acetate and acetone at 160-300 degrees C, and their photocatalytic activities were investigated by the degradation of methyl blue (MB). The as-prepared product exhibited not only excellent photocatalytic property for the degradation of MB, but also high response (1000 ppm of cyclohexene, R-a/R-g = 140) and excellent selectivity for the detection of cyclohexene. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:537 / 543
页数:7
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