Electrolytic preparation and characterization of Ni-Fe-Mo alloys: Cathode materials for alkaline water electrolysis

被引:0
作者
Ramesh, L [1 ]
Sheshadri, BS [1 ]
Mayanna, SM [1 ]
机构
[1] Bangalore Univ, Cent Coll, Dept Post Grad Studies Chem, Bangalore 560001, Karnataka, India
关键词
Ni-Fe-Mo alloys; cathode materials; anomalous codeposition; hydrogen overvoltage; water electrolysis; Tafel slope;
D O I
10.1002/(SICI)1099-114X(199908)23:10<919::AID-ER524>3.0.CO;2-D
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Ni-Fe-Mo alloys have been electroplated by using suitable bath solution and plating conditions. SEM and XRD analysis showed that the deposited alloys are partially amorphous. Polarization studies indicated a dependence of the hydrogen evolution mechanism on temperature and current density. The alloys exhibited sufficiently low hydrogen over voltage even on prolonged electrolysis in 30% KOH. Electrokinetic parameters are evaluated for hydrogen evolution reaction on Ni-Fe-Mo alloys. Copyright (C) 1999 John Wiley & Sons, Ltd.
引用
收藏
页码:919 / 924
页数:6
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