Amphiphilic gradient copolymers: Synthesis, self-assembly, and applications

被引：32
|
作者：
Chen, Yanjun [1 ]
Chen, Hao [1 ]
Feng, Mengran [1 ]
Dong, Yixiao [1 ]
机构：
[1] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
来源：
EUROPEAN POLYMER JOURNAL | 2016年 / 85卷
基金：
中国国家自然科学基金;
关键词：
Amphiphilic gradient copolymer; Self-assembly; Stimuli-responsiveness; LIVING CATIONIC-POLYMERIZATION; ONE-POT SYNTHESIS; RADICAL POLYMERIZATION; BLOCK-COPOLYMERS; DRUG-DELIVERY; COMPATIBILIZATION; STYRENE; BLENDS; MICELLIZATION; METHACRYLATE;
D O I：
10.1016/j.eurpolymj.2016.11.009
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Amphiphilic gradient copolymers vary their monomer composition from hydrophilic units to hydrophobic units gradually along molecular chains. Amphiphilic gradient copolymers can self-assemble to form aggregates in solution. Interstingly, the gradient nature endows their aggregates some different stimuli-responsive factors from block copolymer aggregates, such as inherent thermosensitivity and more sensitive stimuli-responsiveness. Amphiphilic gradient copolymers have been considered as not only an underutilized resource, but also a new functional material of high potential in various fields. The purpose of this review is to take a closer look at synthetic procedures, self-assembly properties and applications of amphiphilic gradient copolymers. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：489 / 498
页数：10
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