Azide rearrangements in electron-deficient systems

被引：232

作者：

Lang, S ^{[1
]}

Murphy, JA

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL SOCIETY REVIEWS | 2006年 / 35卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b505080d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The azide group has a diverse and extensive role in organic chemistry, reflected in the power of azide anion as a strong nucleophile, the role of organic azides as excellent substrates for cycloaddition reactions, the uses of azides as precursors of amines and nitrenes, and azide rearrangements known as the Curtius and Schmidt reactions. In recent years the scope of the Schmidt reaction has begun to be explored in depth, so that it now represents an important reaction in synthetic chemistry. This tutorial review analyses and summarises key recent developments in the field of Schmidt reactions.

引用

页码：146 / 156

页数：11

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