M3+O(-Mn4+)2 clusters in doped MnOx catalysts as promoted active sites for the aerobic oxidation of 5-hydroxymethylfurfural

被引:49
作者
Yu, Kai [1 ,2 ]
Liu, Yaqi [1 ]
Lei, Da [1 ,3 ,4 ]
Jiang, Yuanzhi [3 ,4 ]
Wang, Yanbing [3 ,4 ]
Feng, Yajun [1 ]
Lou, Lan-Lan [2 ,3 ,4 ]
Liu, Shuangxi [3 ,4 ,5 ]
Zhou, Wuzong [2 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, MOE Key Lab Pollut Proc & Environm Criteria, Tianjin 300350, Peoples R China
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[3] Nankai Univ, Inst New Catalyt Mat Sci, Tianjin 300350, Peoples R China
[4] Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, MOE Key Lab Adv Energy Mat Chem, Tianjin 300350, Peoples R China
[5] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
关键词
ENHANCED PSEUDOCAPACITIVE PERFORMANCE; 2,5-FURANDICARBOXYLIC ACID; LOW-TEMPERATURES; PD CATALYSTS; BIOMASS; SUPPORT; FE; CO; CU;
D O I
10.1039/c7cy02455j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Based on various experimental results, M3+O(-Mn4+)(2) clusters in (Fe, Co, Ni)-doped MnOx catalysts were identified as the principal active sites for the aerobic oxidation of 5-hydroxymethylfurfural due to their special properties that make oxygen easy come, easy go'.
引用
收藏
页码:2299 / 2303
页数:5
相关论文
共 21 条
  • [1] Biomass into Chemicals: Aerobic Oxidation of 5-Hydroxymethyl-2-furfural into 2,5-Furandicarboxylic Acid with Gold Nanoparticle Catalysts
    Casanova, Onofre
    Iborra, Sara
    Corma, Avelino
    [J]. CHEMSUSCHEM, 2009, 2 (12) : 1138 - 1144
  • [2] Pd catalysts supported on MnCeOx mixed oxides and their catalytic application in solvent-free aerobic oxidation of benzyl alcohol: Support composition and structure sensitivity
    Chen, Yuanting
    Zheng, Huijian
    Guo, Zhen
    Zhou, Chunmei
    Wang, Chuan
    Borgna, Armando
    Yang, Yanhui
    [J]. JOURNAL OF CATALYSIS, 2011, 283 (01) : 34 - 44
  • [3] Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts
    Davis, Sara E.
    Houk, Levi R.
    Tamargo, Erin C.
    Datye, Abhaya K.
    Davis, Robert J.
    [J]. CATALYSIS TODAY, 2011, 160 (01) : 55 - 60
  • [4] Oxidation of 5-hydroxymethylfurfural to maleic anhydride with molecular oxygen
    Du, Zhongtian
    Ma, Jiping
    Wang, Feng
    Liu, Junxia
    Xu, Jie
    [J]. GREEN CHEMISTRY, 2011, 13 (03) : 554 - 557
  • [5] Tuning chemical bonding of MnO2 through transition-metal doping for enhanced CO oxidation
    Gao, Jiajian
    Jia, Chunmiao
    Zhang, Liping
    Wang, Hongming
    Yang, Yanhui
    Hung, Sung-Fu
    Hsu, Ying-Ya
    Liu, Bin
    [J]. JOURNAL OF CATALYSIS, 2016, 341 : 82 - 90
  • [6] Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over MnOx-CeO2 composite catalysts
    Han, Xuewang
    Li, Chaoqun
    Liu, Xiaohui
    Xia, Qineng
    Wang, Yanqin
    [J]. GREEN CHEMISTRY, 2017, 19 (04) : 996 - 1004
  • [7] Heterogeneously-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid with MnO2
    Hayashi, Eri
    Komanoya, Tasuku
    Kamata, Keigo
    Hara, Michikazu
    [J]. CHEMSUSCHEM, 2017, 10 (04) : 654 - 658
  • [8] Enhanced Pseudocapacitive Performance of α-MnO2 by Cation Preinsertion
    Jabeen, Nawishta
    Xia, Qiuying
    Savilov, Serguei V.
    Aldoshin, Sergey M.
    Yu, Yan
    Xia, Hui
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (49) : 33732 - 33740
  • [9] Facet Effect of Single-Crystalline Pd Nanocrystals for Aerobic Oxidation of 5-Hydroxymethyl-2-furfural
    Lei, Da
    Yu, Kai
    Li, Meng-Ru
    Wang, Yuling
    Wang, Qi
    Liu, Tong
    Liu, Pengkun
    Lou, Lan-Lan
    Wang, Guichang
    Liu, Shuangxi
    [J]. ACS CATALYSIS, 2017, 7 (01): : 421 - 432
  • [10] Selective oxidation of 5-hydroxymethyl furfural over non-precious metal heterogeneous catalysts
    Neatu, Florentina
    Marin, Roxana Simona
    Florea, Mihaela
    Petrea, Nicoleta
    Pavel, Octavian Dumitru
    Parvulescu, Vasile I.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 180 : 751 - 757