M3+O(-Mn4+)2 clusters in doped MnOx catalysts as promoted active sites for the aerobic oxidation of 5-hydroxymethylfurfural

被引:49
作者
Yu, Kai [1 ,2 ]
Liu, Yaqi [1 ]
Lei, Da [1 ,3 ,4 ]
Jiang, Yuanzhi [3 ,4 ]
Wang, Yanbing [3 ,4 ]
Feng, Yajun [1 ]
Lou, Lan-Lan [2 ,3 ,4 ]
Liu, Shuangxi [3 ,4 ,5 ]
Zhou, Wuzong [2 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, MOE Key Lab Pollut Proc & Environm Criteria, Tianjin 300350, Peoples R China
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[3] Nankai Univ, Inst New Catalyt Mat Sci, Tianjin 300350, Peoples R China
[4] Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, MOE Key Lab Adv Energy Mat Chem, Tianjin 300350, Peoples R China
[5] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
关键词
ENHANCED PSEUDOCAPACITIVE PERFORMANCE; 2,5-FURANDICARBOXYLIC ACID; LOW-TEMPERATURES; PD CATALYSTS; BIOMASS; SUPPORT; FE; CO; CU;
D O I
10.1039/c7cy02455j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Based on various experimental results, M3+O(-Mn4+)(2) clusters in (Fe, Co, Ni)-doped MnOx catalysts were identified as the principal active sites for the aerobic oxidation of 5-hydroxymethylfurfural due to their special properties that make oxygen easy come, easy go'.
引用
收藏
页码:2299 / 2303
页数:5
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