Effects of Nb and C additions on the crystallization behavior, microstructure and magnetic properties of B-rich nanocrystalline Nd-Fe-B ribbons

被引:13
作者
Li, Shun [1 ]
Bai, Shuxin [1 ]
Zhang, Hong [1 ]
Chen, Ke [1 ]
Xiao, Jiayu [1 ]
机构
[1] Natl Univ Def Technol, Dept Mat Engn & Appl Chem, Changsha 410073, Hunan, Peoples R China
关键词
Nanocomposite magnet; Crystallization behavior; Magnetic properties; NANOCOMPOSITE MAGNETS; TI ADDITIONS; ALLOYS;
D O I
10.1016/j.jallcom.2008.02.054
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of Nb and C additions on the crystallization behavior, microstructure and magnetic properties of B-rich Nd9.4Fe79.6-xNbxB11-yCy (x = 0, 2, and 4; y = 0, 0.5, and 1.5) alloy ribbons have been investigated. The results show that Nb and C additions change the crystallization behavior of Nd9.4Fe79.6B11, avoid the formation of metastable Nd2Fe23B3 phase. leading to the simultaneously precipitation of alpha-Fe and Nd2Fe14B phases. The results also show that Nb and C additions suppress the formation and growth of the soft alpha-Fe phases, leading to the presence of a large amount of Nd2Fe14B phases. Nb and C additions also refine the structure, and thus increase the exchange coupling interaction between the soft and hard phases. Excellent magnetic properties of B-r = 0.85T, H-i(c) = 1106 kA/m, and (BH)(max) = 117 kJ/m(3) have been achieved in Nd9.4Fe75.6Nb4B10.5C0.5 alloy ribbons. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:141 / 144
页数:4
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