Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity

被引：91
|
作者：
Munha, Rui F. [1 ]
Zarkesh, Ryan A. [1 ]
Heyduk, Alan F. [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 11期
基金：
美国国家科学基金会;
关键词：
CARBON-MONOXIDE CLEAVAGE; HYDROGEN BOND ACTIVATION; C-H ACTIVATION; ATOM-TRANSFER; TRAPPING REACTIONS; OXIDATIVE ADDITION; IMIDO COMPLEXES; TITANIUM IMIDO; BASE-FREE; DICYCLOPENTADIENYLTITANIUM COMPLEXES;
D O I：
10.1039/c2dt32063k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Group- and atom-transfer is an attractive reaction class for the preparation of value-added organic substrates. Despite a wide variety of known early-transition metal oxo and imido complexes, these species have received limited attention for atom- and group-transfer reactions, owing to the lack of an accessible metal-based two-electron redox couple. Recently it has been shown that redox-active ligands can support the multi-electron changes required to promote group-transfer reactivity, opening up new avenues for group- and atom-transfer catalyst design. This Perspective article provides an overview of group transfer reactivity in early-transition metal complexes supported by traditional ligand platforms, followed by recent advances in the atom- and group-transfer reactivity of d(0) metal complexes containing redox-active ligands.
引用
收藏
页码：3751 / 3766
页数：16
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