Electron energy-loss spectra of graphene oxide for the determination of oxygen functionalities

被引：46

作者：

D'Angelo, D. ^{[1
]}

Bongiorno, C. ^{[1
]}

Amato, M. ^{[2
]}

Deretzis, I. ^{[1
]}

La Magna, A. ^{[1
]}

Compagnini, G. ^{[3
]}

Spano, S. F. ^{[3
]}

Scalese, S. ^{[1
]}

机构：

[1] CNR IMM, I-95121 Catania, Italy

[2] Distretto Tecnol Sicilia Micro & Nano Sistemi Sca, I-95121 Catania, Italy

[3] Univ Catania, Dip Sci Chim, I-95125 Catania, Italy

来源：

CARBON | 2015年 / 93卷

关键词：

NANOSHEETS; REDUCTION; DYE;

D O I：

10.1016/j.carbon.2015.06.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphene based materials for large-scale production can be obtained starting from graphene oxide (GO) by means of suitable treatments in order to reduce the number of oxygen functional groups. The composition and the structure of GO and reduced GO depend on the synthesis and reduction methodologies. In this work, GO was prepared by a modified Hummers method and reduced by pulsed laser irradiation using visible wavelength (532 nm). Transmission electron microscopy analyses were performed and dual electron energy-loss spectra were acquired in different regions of GO and reduced GO flakes. Experimental results show a series of characteristic peaks related to C and O K-edge shells. Density functional theory calculations of the high-loss region of the electron energy loss spectra at atomic level enable a reliable correlation between the observed experimental peaks to the presence of different oxygen functional groups on the graphene surface and the corresponding atomic configurations. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：1034 / 1041

页数：8

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