Synthesis, structure and reactivity of organogold compounds of relevance to homogeneous gold catalysis

被引:249
作者
Hashmi, A. Stephen K. [1 ]
Ramamurthi, Tanuja Dondeti [1 ]
Rominger, Frank [1 ]
机构
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
关键词
Organogold compounds; Boronic acids; Halogenations; Michael acceptors; Protodeauration; GOLD(I)-CATALYZED FORMATION; COMPLEXES; GOLD(III); AURATION; ARENES;
D O I
10.1016/j.jorganchem.2008.11.054
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Organogold(I) phosphane complexes were prepared, their structure was investigated and their reactivity in reactions with Michael acceptors, sources of electrophilic halogens and protons were investigated. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:592 / 597
页数:6
相关论文
共 47 条
[1]   The first fluoride-free Hiyama reaction of vinylsiloxanes promoted by sodium hydroxide in water [J].
Alacid, Emilio ;
Najera, Carmen .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (15) :2085-2091
[2]   Alternative synthetic methods through new developments in catalysis by gold [J].
Arcadi, Antonio .
CHEMICAL REVIEWS, 2008, 108 (08) :3266-3325
[3]   Transferring iodine: more than a simple functional group exchange in organic synthesis [J].
Barluenga, J .
PURE AND APPLIED CHEMISTRY, 1999, 71 (03) :431-436
[4]   Synthesis, structure, and reactions of a binuclear gold(I)-gold(III) complex containing bridging and bidentate (2-diphenylphosphino-6-methyl)phenyl groups [J].
Bhargava, SK ;
Mohr, F ;
Bennett, MA ;
Welling, LL ;
Willis, AC .
ORGANOMETALLICS, 2000, 19 (26) :5628-5635
[5]   Gold(I)-catalyzed stereoselective formation of functionalized 2,5-dihydrofurans [J].
Buzas, A ;
Istrate, F ;
Gagosz, F .
ORGANIC LETTERS, 2006, 8 (09) :1957-1959
[6]   Gold(I)-catalyzed formation of 4-alkylidene-1,3-dioxolan-2-ones from propargylic tert-butyl carbonates [J].
Buzas, A ;
Gagosz, F .
ORGANIC LETTERS, 2006, 8 (03) :515-518
[7]   Gold(I)-catalyzed formation of 5-methylene-1,3-oxazolidin-2-ones [J].
Buzas, Andrea ;
Gagosz, Fabien .
SYNLETT, 2006, (17) :2727-2730
[8]   Supported gold catalyzes the homocoupling of phenylboronic acid with high conversion and selectivity [J].
Carrettin, S ;
Guzman, J ;
Corma, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (15) :2242-2245
[9]  
Carrettin S., 2005, ANGEW CHEM, V117, P2282
[10]  
Cooley JH, 2003, CHEM ED, V8, P309