Formation and characterization of HUF and DUF in solid argon

被引：7

作者：

Vent-Schmidt, Thomas ^{[1
]}

Hunt, Rodney Dale ^{[2
]}

Andrews, Lester ^{[1
,3
]}

Riedel, Sebastian ^{[1
]}

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA

[3] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 37期

关键词：

TRANSFORM INFRARED-SPECTRA; BOND COVALENT RADII; URANIUM; MOLECULES; THERMOCHEMISTRY; COMPLEXES;

D O I：

10.1039/c3cc41379a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of laser-ablated U atoms with HF and DF in condensing and solid rare gas produce HUF and DUF as the major new products based on close agreement between observed and calculated vibrational frequencies and deuterium shifts for U-H and U-F stretching modes at 1383 and 544 cm(-1), respectively.

引用

页码：3863 / 3865

页数：3

共 22 条

[1] Matrix infrared spectra and density functional calculations of transition metal hydrides and dihydrogen complexes
Andrews, L
[J]. CHEMICAL SOCIETY REVIEWS, 2004, 33 (02) : 123 - 132
[2] FOURIER-TRANSFORM INFRARED-SPECTRA OF (HF)N SPECIES IN SOLID ARGON
ANDREWS, L
JOHNSON, GL
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (03) : 425 - 432
[3] FAR INFRARED-SPECTRA OF (HF)2 AND (HF)3 IN SOLID ARGON
ANDREWS, L
DAVIS, SR
HUNT, RD
[J]. MOLECULAR PHYSICS, 1992, 77 (05) : 993 - 1003
[4] FOURIER-TRANSFORM INFRARED-SPECTRA OF HF COMPLEXES IN SOLID ARGON
ANDREWS, L
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (14) : 2940 - 2949
[5] Spectroscopic and Theoretical Investigations of UF and UF+
Antonov, Ivan O.
Heaven, Michael C.
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (39) : 9684 - 9694
[6] Density functional investigations of the properties and thermochemistry of UFn and UCln (n=1,...,6)
Batista, ER
Martin, RL
Hay, PJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (22) : 11104 - 11111
[7] Fishlock D, 2004, CHEM WORLD-UK, V1, P46
[8] Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character
Gong, Yu
Wang, Xuefeng
Andrews, Lester
Schloeder, Tobias
Riedel, Sebastian
[J]. INORGANIC CHEMISTRY, 2012, 51 (12) : 6983 - 6991
[9] Harrington C.D., 1959, Uranium production technology
[10] REDETERMINATION OF THE THERMOCHEMISTRY OF GASEOUS UF5, UF2, AND UF
HILDENBRAND, DL
LAU, KH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (02) : 1420 - 1425

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