Living/controlled radical copolymerization of N-phenylmaleimide and styrene using Frechet-type dendritic initiators

被引：1

作者：

Zhao, YL ^{[1
]}

Jiang, J ^{[1
]}

Liu, HW ^{[1
]}

Chen, CF ^{[1
]}

Xi, F ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

SCIENCE IN CHINA SERIES B-CHEMISTRY | 2002年 / 45卷 / 02期

关键词：

dendritic-linear block copolymer; macroinitiator; N-phenylmaleimide; styrene; atom transfer radical copolymerization;

D O I：

10.1360/02yb9019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyarylether dendrons as macroinitiators for the "living"/controlled free radical copolymerization of N-phenylmaleimide (PhMI) and styrene (St) have been demonstrated. The copolymerization was carried out in bulk or anisole with CuBr/bipy catalyst at 100-130degreesC. It is found that the resulting copolymers possess predetermined molecular weights and narrower polydispersities (1.18 < M-w/M-n<1.32). The effects of reaction temperature and monomer feed on the copolymerization kinetics were investigated in detail. By using the Fineman-Ross method, the apparent monomer reactivity ratios for the atom transfer radical copolymerization of PhMI and St were determined to be r(PhMI) = 0.0207, and r(St) = 0.0484, respectively.

引用

页码：135 / 142

页数：8

共 44 条

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