Structural Variety of Cobalt(II), Nickel(II), Zinc(II), and Cadmium(II) Complexes with 4,4′-Azopyridine: Synthesis, Structure and Luminescence Properties

被引：20
作者：
Pladzyk, Agnieszka [1 ]
Ponikiewski, Lukasz [1 ]
Dolega, Anna [1 ]
Slowy, Klaudia [1 ]
Sokolowska, Agata [1 ]
Dziubinska, Katarzyna [1 ]
Hnatejko, Zbigniew [2 ]
机构：
[1] Gdask Univ Technol, Dept Inorgan Chem, PL-80233 Gdansk, Poland
[2] Adam Mickiewicz Univ, Dept Rare Earths, PL-61414 Poznan, Poland
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2015年 / 10卷 / 11期
关键词：
coordination complexes; crystal structures; luminescence; spectroscopic studies; structure elucidation; METAL-ORGANIC FRAMEWORKS; SILICON-SULFUR-COMPOUNDS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; ALIPHATIC DIAMINES; LIGANDS; CD(II); CO(II); FLUORESCENCE;
D O I：
10.1002/asia.201500652
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Self-assembled bi- and polymetallic complexes of Co-II, Ni-II, Zn-II, and Cd-II were obtained by the reaction of 4,4-azopyridine (azpy) with metal tri-tert-butoxysilanethiolates (Co, 1; Cd, 2), acetylacetonates (Ni, 3; Zn, 4), and acetates (Cd, 5). All compounds were characterized by single-crystal X-ray structure analysis, elemental analysis, FTIR spectroscopy, and thermogravimetry. Complexes1, 2 and 4, 5 exhibit diverse structural conformations: 1 is bimetallic, 2 and 4 are 1D coordination polymers, and 5 is a 2D coordination framework formed from bimetallic units. The obtained complexes contain metal atoms bridged by a molecule of azpy. The luminescent properties of 1-5 were investigated in the solid state.
引用
收藏
页码：2388 / 2396
页数：9
相关论文
共 63 条
[11]   Rational Construction of 3D Pillared Metal-Organic Frameworks: Synthesis, Structures, and Hydrogen Adsorption Properties [J].
Chang, Ze ;
Zhang, Da-Shuai ;
Chen, Qiang ;
Li, Rui-Fang ;
Hu, Tong-Liang ;
Bu, Xian-He .
INORGANIC CHEMISTRY, 2011, 50 (16) :7555-7562
[12]   Self-assembly of a luminescent Zinc(II) complex: a supramolecular host-guest fluorescence signaling system for selective nitrobenzene inclusion [J].
Das, Sanjib ;
Bharadwaj, Parimal K. .
INORGANIC CHEMISTRY, 2006, 45 (14) :5257-5259
[13]   μ-4,4′-bipyridyl-1:2κ2N:N′-methanol-2κO-tetrakis(tri-tert-butoxysilanethiol-ato)-1κ4O,S;2κ2S-dizinc(II) [J].
Dolega, Anna ;
Baranowska, Katarzyna .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M616-U131
[14]   (μ-4,4′-bipyridyl-κ2N:N′)bis[bis(tri-tert-butoxysilanethiolato-κ2S,O)cadmium(II)] toluene disolvate [J].
Dolega, Anna ;
Baranowska, Katarzyna ;
Pladzyk, Agnieszka .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 :M3072-U1925
[15]   REFERENCE MATERIALS FOR FLUORESCENCE MEASUREMENT [J].
EATON, DF .
PURE AND APPLIED CHEMISTRY, 1988, 60 (07) :1107-1114
[16]   Temperature-Dependent in Situ Reduction of 4,4′-Azobispyridine via Solvothermal Reaction [J].
Gai, Yan-Li ;
Jiang, Fei-Long ;
Xiong, Ke-Cai ;
Chen, Lian ;
Yuan, Da-Qiang ;
Zhang, Lin-Jie ;
Zhou, Kang ;
Hong, Mao-Chun .
CRYSTAL GROWTH & DESIGN, 2012, 12 (04) :2079-2088
[17]   Syntheses, structures, and photoluminescent properties of a series of zinc(II)-3-amino-1,2,4-triazolate coordination polymers constructed by varying carboxylate anions [J].
Gao, JinYing ;
Wang, Ning ;
Xiong, XiaHua ;
Chen, ChuJun ;
Xie, WeiPing ;
Ran, XingRui ;
Long, Yi ;
Yue, ShanTang ;
Liu, YingLiang .
CRYSTENGCOMM, 2013, 15 (17) :3261-3270
[18]   Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks [J].
He, JH ;
Yu, JH ;
Zhang, YT ;
Pan, QH ;
Xu, RR .
INORGANIC CHEMISTRY, 2005, 44 (25) :9279-9282
[19]   CONTRIBUTIONS TO THE CHEMISTRY OF SILICON-SULFUR COMPOUNDS .23. HYDROLYSIS REACTION OF SILANETHIOLS [J].
HERMAN, A ;
BECKER, B ;
WOJNOWSKI, W .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1979, 450 (MAR) :178-182
[20]   Luminescent metal-organic frameworks for chemical sensing and explosive detection [J].
Hu, Zhichao ;
Deibert, Benjamin J. ;
Li, Jing .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5815-5840
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