N-Formylation of Amines by Methanol Activation

被引：151

作者：

Ortega, Nuria ^{[1
]}

Richter, Christian ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Organ Chem Inst, D-48149 Munster, Germany

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 07期

关键词：

EFFICIENT HYDROGEN-PRODUCTION; DIRECT AMIDE SYNTHESIS; ASYMMETRIC HYDROGENATION; CATALYTIC-HYDROGENATION; AEROBIC OXIDATION; CARBON-DIOXIDE; RUTHENIUM; ALCOHOLS; ESTERS; DEHYDROGENATION;

D O I：

10.1021/ol400639m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The homogeneous catalyzed dehydrogenation of methanol In a synthetically valuable cross-coupling reaction was achieved. By the use of a simple ruthenium-N-heterocyclic carbene complex, MeOH and primary or secondary amines can be converted into formamides.

引用

页码：1776 / 1779

页数：4

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