Simulation-Assisted Self-Assembly of Multicomponent Polymers into Hierarchical Assemblies with Varied Morphologies

被引：102

作者：

Cai, Chunhua ^{[1
]}

Li, Yongliang ^{[1
]}

Lin, Jiaping ^{[1
]}

Wang, Liquan ^{[1
]}

Lin, Shaoliang ^{[1
]}

Wang, Xiao-Song ^{[2
]}

Jiang, Tao ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Shanghai Key Lab Adv Polymer Mat, State Key Lab Bioreactor Engn, Key Lab Ultrafine Mat,Sch Mat Sci & Engn,Minist E, Shanghai 200237, Peoples R China

[2] Univ Waterloo, WIN, Dept Chem, Waterloo, ON N2L 3G1, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 30期

基金：

加拿大自然科学与工程研究理事会; 中国国家自然科学基金;

关键词：

block copolymers; hierarchical assembly; homopolymers; polypeptides; COIL DIBLOCK COPOLYMERS; BLOCK-COPOLYMERS; DILUTE-SOLUTION; MICELLES; NANOPARTICLES; NANOSTRUCTURES; COMPLEXES; MECHANISM; VESICLES; BEHAVIOR;

D O I：

10.1002/anie.201210024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As you like it: The synthesis of supramolecular hierarchical nanostructures with designed morphologies has been realized through computer-simulation-guided multicomponent assembly of polypeptide-based block copolymers and homopolymers. By adjusting the attraction between hydrophobic polypeptide rods, as well as other parameters such as the molar ratio of copolymers and the rigidity of polymers, a variety of morphologies were obtained. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7732 / 7736

页数：5

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