A tetranuclear Cu4(μ3-OH)2-based metal-organic framework (MOF) with sulfonate-carboxylate ligands for proton conduction

被引：128

作者：

Dong, Xi-Yan ^{[1
,2
]}

Wang, Rui ^{[1
]}

Li, Jia-Bin ^{[1
]}

Zang, Shuang-Quan ^{[1
]}

Hou, Hong-Wei ^{[1
]}

Mak, Thomas C. W. ^{[1
,3
,4
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

[2] Henan Polytech Univ, Sch Phys & Chem, Jiaozuo 454000, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[4] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 90期

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; WATER; IONS; TRANSFORMATION; MECHANISM; CLUSTERS; BEHAVIOR;

D O I：

10.1039/c3cc46226a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new tetranuclear Cu-4(mu(3)-OH)(2)-based metal-organic framework (MOF) with sulfonate-carboxylate ligands features large hydrophilic channels. This MOF exhibits proton conductivity over 10(-3) S cm(-1) at 85-100 degrees C and 98% relative humidity and colossal dielectric constant.

引用

页码：10590 / 10592

页数：3

共 33 条

[1] Protonic conductivity of layered zirconium phosphonates containing -SO3H groups .3. Preparation and characterization of gamma-zirconium sulfoaryl phosphonates [J].

Alberti, G ;

Boccali, L ;

Casciola, M ;

Massinelli, L ;

Montoneri, E .

SOLID STATE IONICS, 1996, 84 (1-2) :97-104

[2] Temperature-dependent conductivity of Emim+ (Emim+=1-ethyl-3-methyl imidazolium) confined in channels of a metal-organic framework [J].

Chen, Wen-Xian ;

Xu, Hao-Ran ;

Zhuang, Gui-Lin ;

Long, La-Sheng ;

Huang, Rong-Bin ;

Zheng, Lan-Sun .

CHEMICAL COMMUNICATIONS, 2011, 47 (43) :11933-11935

[3] Dielectric properties of porous molecular crystals that contain polar molecules [J].

Cui, HB ;

Takahashi, K ;

Kano, Y ;

Kobayashi, H ;

Wang, ZM ;

Kobayashi, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6508-6512

[4] H3O2 Bridging Ligand in a Metal-Organic Framework. Insight into the Aqua-Hydroxo⇆Hydroxyl Equilibrium: A Combined Experimental and Theoretical Study [J].

D'Vries, Richard F. ;

de la Pena-O'Shea, Victor A. ;

Snejko, Natalia ;

Iglesias, Marta ;

Gutierrez-Puebla, Enrique ;

Angeles Monge, M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (15) :5782-5792

[5] Reversible phase transformation in proton conducting Strandberg-type POM based metal organic material [J].

Dey, Chandan ;

Kundu, Tanay ;

Banerjee, Rahul .

CHEMICAL COMMUNICATIONS, 2012, 48 (02) :266-268

[6] Ferroelectric Switchable Behavior through Fast Reversible De/adsorption of Water Spirals in a Chiral 3D Metal-Organic Framework [J].

Dong, Xi-Yan ;

Li, Bo ;

Ma, Bin-Bin ;

Li, Shi-Jun ;

Dong, Ming-Ming ;

Zhu, Yan-Yan ;

Zang, Shuang-Quan ;

Song, You ;

Hou, Hong-Wei ;

Mak, Thomas C. W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (28) :10214-10217

[7] Immobilization of sodium ions on the pore surface of a porous coordination polymer [J].

Horike, S ;

Matsuda, R ;

Tanaka, D ;

Mizuno, M ;

Endo, K ;

Kitagawa, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (13) :4222-4223

[8]

Hurd JA, 2009, NAT CHEM, V1, P705, DOI [10.1038/NCHEM.402, 10.1038/nchem.402]

[9] The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant [J].

Ji, Wen-Juan ;

Zhai, Quan-Guo ;

Li, Shu-Ni ;

Jiang, Yu-Cheng ;

Hu, Man-Cheng .

CHEMICAL COMMUNICATIONS, 2011, 47 (13) :3834-3836

[10] Synthesis and Characterization of Ionic Conducting Sulfonated Polybenzimidazoles [J].

Jouanneau, Julien ;

Gonon, Laurent ;

Gebel, Gerard ;

Martin, Vincent ;

Mercier, Regis .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (08) :1732-1742

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