Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

被引：36
|
作者：
Wu, Xin [1 ]
Zhang, Hua-Bin [1 ]
Xu, Zhong-Xuan [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 91期
关键词：
METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; CHIRAL INFORMATION; CRYSTALLIZATION; ADSORPTION; CATALYSIS; POROSITY; POLYMER; NETS;
D O I：
10.1039/c5cc06501a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two three-dimensional (3D) homochiral metal-organic frameworks, integrating double helical chains based on enantiopure ligands and single helical structures braided by 4,4'-bipyridine (bipy) and cadmium clusters, have been synthesized successfully, as a result of complete asymmetric induction between the two types of helix.
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收藏
页码：16331 / 16333
页数：3
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