Self-Assembled Metal Atom Chains on Graphene Nanoribbons

被引:77
作者
Choi, Seon-Myeong [1 ]
Jhi, Seung-Hoon [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Phys, Pohang 790784, South Korea
关键词
D O I
10.1103/PhysRevLett.101.266105
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Electronic and magnetic properties of alkali and alkaline-earth metal doped graphene nanoribbons (GNRs) are studied by the pseudopotential density functional method. Strong site dependence is observed in metal adsorption on GNRs, and the adsorbed metal atoms are found to spontaneously form atomic chains in a particular form of GNRs. Such doped GNRs exhibit intriguing magnetic properties such as hysteresis and spin compensation as metal atoms switch from one edge to another at alternating gate voltages. Our study shows that the metal atoms can be used as reagents that can identify the edge atomic structures of GNRs and also as gate-driven spin valves that control the spin current in GNRs.
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页数:4
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共 25 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Condensation of Na metal on graphite studied by photoemission -: art. no. 235416 [J].
Breitholtz, M ;
Kihlgren, T ;
Lindgren, SÅ ;
Walldén, L .
PHYSICAL REVIEW B, 2003, 67 (23)
[3]   Alkali metal adsorption on graphite: a review [J].
Caragiu, M ;
Finberg, S .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (35) :R995-R1024
[4]   Gate-tunable graphene spin valve [J].
Cho, Sungjae ;
Chen, Yung-Fu ;
Fuhrer, Michael S. .
APPLIED PHYSICS LETTERS, 2007, 91 (12)
[5]   PSEUDOPOTENTIALS AND TOTAL ENERGY CALCULATIONS [J].
COHEN, ML .
PHYSICA SCRIPTA, 1982, T1 :5-10
[6]   SPIN-ORBIT INTERACTION IN GRAPHITE [J].
DRESSELHAUS, GF ;
DRESSELHAUS, MS ;
MAVROIDES, JG .
CARBON, 1966, 4 (03) :433-+
[7]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[8]   Energy band-gap engineering of graphene nanoribbons [J].
Han, Melinda Y. ;
Oezyilmaz, Barbaros ;
Zhang, Yuanbo ;
Kim, Philip .
PHYSICAL REVIEW LETTERS, 2007, 98 (20)
[9]   Graphene spin valve devices [J].
Hill, Ernie W. ;
Geim, Andre K. ;
Novoselov, Konstantin ;
Schedin, Frederik ;
Blake, Peter .
IEEE TRANSACTIONS ON MAGNETICS, 2006, 42 (10) :2694-2696
[10]   TEMPERATURE-DEPENDENT BEHAVIOR IN THE ADSORPTION OF SUBMONOLAYER POTASSIUM ON GRAPHITE [J].
HOCK, KM ;
PALMER, RE .
SURFACE SCIENCE, 1993, 284 (03) :349-360