Modeling of mass and energy transfers in a high temperature membrane electrolyser

被引：6

作者：

Dumortier, M. ^{[1
,2
]}

Lacroix, O. ^{[2
]}

Sanchez-Marcano, J. ^{[1
]}

机构：

[1] Univ Montpellier 2, CNRS ENSCM UM2, IEM, UMR 5635, F-34095 Montpellier, France

[2] AREVA NP, Ctr Tech, F-34095 Montpellier 5, France

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 09期

关键词：

SOEC; Electrochemical membrane reactor; Cermet; Mass and heat transfer; Modeling; HYDROGEN-PRODUCTION; STEAM ELECTROLYSIS; SOLID-ELECTROLYTE; 3-PHASE ELECTRODE; PROTON; CELL; TRANSPORT;

D O I：

10.1016/j.ijhydene.2013.10.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work we report the modeling and simulation of a Solid Oxide Electrolysis Cell (SOEC) membrane reactor for hydrogen production. The reactor was composed of two compartments separated by a dense perovskite membrane and cermet electrodes. The model which includes mass and heat transfers and electrochemical reaction rate was validated with experimental results obtained from the literature. The simulation allowed studying the influence of the structural parameters of the electrode (grain radii, volume and conductivity ratios of the metallic and ceramic phases) on the electrochemical reaction rate through the thickness of the anodic cermet. The simulation of heat transfers permitted to obtain the temperature profile through the different membrane reactor compartments which depends mainly on the gas hydrodynamics inside the anodic compartment. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：4683 / 4690

页数：8

共 17 条

[1] Hydrogen production in solid electrolyte membrane reactors (SEMRs) [J].

Athanassiou, C. ;

Pekridis, G. ;

Kaklidis, N. ;

Kalimeri, K. ;

Vartzoka, S. ;

Marnellos, G. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (01) :38-54

[2] Radiation heat transfer in SOFC materials and components [J].

Damm, DL ;

Fedorov, AG .

JOURNAL OF POWER SOURCES, 2005, 143 (1-2) :158-165

[3]

du Plessis E, 2009, CHEM ENG SCI, P2541

[4] Energy transport inside a three-phase electrode and application to a proton-conducting solid oxide electrolysis cell [J].

Dumortier, Mikael ;

Sanchez, Jose ;

Keddam, Michel ;

Lacroix, Olivier .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (06) :2610-2623

[5] Theoretical considerations on the modelling of transport in a three-phase electrode and application to a proton conducting solid oxide electrolysis cell [J].

Dumortier, Mikael ;

Sanchez, Jose ;

Keddam, Michel ;

Lacroix, Olivier .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (16) :11579-11594

[6] Hydrogen production by high temperature electrolysis with nuclear reactor [J].

Fujiwara, Seiji ;

Kasai, Shigeo ;

Yamauchi, Hiroyuki ;

Yamada, Kazuya ;

Makino, Shinichi ;

Matsunaga, Kentaro ;

Yoshino, Masato ;

Kameda, Tsuneji ;

Ogawa, Takashi ;

Momma, Shigeki ;

Hoashi, Eiji .

PROGRESS IN NUCLEAR ENERGY, 2008, 50 (2-6) :422-426

[7] Simulation of a high temperature electrolyzer [J].

Grondin, Dominique ;

Deseure, Jonathan ;

Brisse, Annabelle ;

Zahid, Mohsine ;

Ozil, Patrick .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2010, 40 (05) :933-941

[8] Heat/mass transfer in porous electrodes of fuel cells [J].

Hwang, J. J. ;

Chen, P. Y. .

INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2006, 49 (13-14) :2315-2327

[9] HIGH-TEMPERATURE STEAM ELECTROLYSIS USING SRCEO3-BASED PROTON CONDUCTIVE SOLID ELECTROLYTE [J].

IWAHARA, H ;

UCHIDA, H ;

YAMASAKI, I .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1987, 12 (02) :73-77

[10] Computational fluid dynamics analysis of solid oxide electrolysis cells with delaminations [J].

Jin, Xinfang ;

Xue, Xingjian .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (14) :7321-7328

← 1 2 →