The ammonium-promoted formylation of indoles by DMSO and H2O

被引：99

作者：

Fei, Haiyang ^{[1
]}

Yu, Jintao ^{[1
]}

Jiang, Yan ^{[1
]}

Guo, Huan ^{[1
]}

Cheng, Jiang ^{[1
,2
]}

机构：

[1] Changzhou Univ, Jiangsu Prov Key Lab Fine Petrochem Engn, Sch Petrochem Engn, Changzhou 213164, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 41期

基金：

中国国家自然科学基金;

关键词：

PUMMERER REACTION; DIMETHYL-SULFOXIDE; SULFONIUM SALTS; OXYGEN-EXCHANGE; SULFIDES; CARBOCYCLES; MECHANISMS; SOLVOLYSIS; TRANSFERS;

D O I：

10.1039/c3ob41510d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

DMSO and H2O is an efficient combination in the NH4OAc-promoted formylation of indole, where DMSO serves as a C1 carbon source. The mechanism study reveals that the procedure involves a usual and unusual Pummerer reaction.

引用

页码：7092 / 7095

页数：4

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