SO3H and NH2+ functional carbon-based solid acid catalyzed transesterification and biodiesel production

被引:9
作者
Cai, Liangzhen [1 ]
Meng, Decai [1 ]
Zhan, Shaoqi [1 ]
Yang, Xiaoxia [1 ]
Liu, Taoping [2 ]
Pu, Huiming [2 ]
Tao, Xiaochun [1 ]
机构
[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
[2] Suzhou Eleco Chem Ind CO Ltd, Kunshan 215341, Jiangsu, Peoples R China
关键词
CARBOXYLIC-ACIDS; SOYBEAN OIL; ESTERIFICATION;
D O I
10.1039/c5ra13839f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A SO3H and NH2+ functional carbon-based solid acid was used as a highly active heterogeneous catalyst for the transesterification of various carboxylic methyl esters with alcohols under mild conditions. It also showed high catalytic performance for transesterification of triolein with methanol or isopropanol. Furthermore, it was able to catalyze simultaneous esterification and transesterification of rice oil and butter respectively, the yields of biodiesel obtained were up to 94%, and the catalyst could be easily recovered and reused more than ten times without loss of activity, which indicated the carbon-based solid acid was a potential catalyst for the biodiesel industry.
引用
收藏
页码:72146 / 72149
页数:4
相关论文
共 26 条
[1]   Fast formation of high-purity methyl esters from vegetable oils [J].
Boocock, DGB ;
Konar, SK ;
Mao, V ;
Lee, C ;
Buligan, S .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1998, 75 (09) :1167-1172
[2]   Polymer-supported O-alkylisoureas:: Useful reagents for the O-alkylation of carboxylic acids [J].
Crosignani, S ;
White, PD ;
Linclau, B .
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (18) :5897-5905
[3]  
FILIP V, 1992, REV FR CORPS GRAS, V39, P91
[4]   TRANSESTERIFICATION KINETICS OF SOYBEAN OIL [J].
FREEDMAN, B ;
BUTTERFIELD, RO ;
PRYDE, EH .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1986, 63 (10) :1375-1380
[5]   Esterification and transesterification of renewable chemicals [J].
Hoydonckx, HE ;
De Vos, DE ;
Chavan, SA ;
Jacobs, PA .
TOPICS IN CATALYSIS, 2004, 27 (1-4) :83-96
[6]   Dehydrative condensation catalyses [J].
Ishihara, Kazuaki .
TETRAHEDRON, 2009, 65 (06) :1085-1109
[7]   USE OF BRANCHED-CHAIN ESTERS TO REDUCE THE CRYSTALLIZATION TEMPERATURE OF BIODIESEL [J].
LEE, I ;
JOHNSON, LA ;
HAMMOND, EG .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1995, 72 (10) :1155-1160
[8]   Transesterification of soybean oil to biodiesel with Zn/I2 catalyst [J].
Li, HT ;
Xie, WL .
CATALYSIS LETTERS, 2006, 107 (1-2) :25-30
[9]   Fuel structure and properties of biodiesel produced by the peroxidation process [J].
Lin, Cherng-Yuan ;
Lin, Hsiu-An ;
Hung, Lang-Bang .
FUEL, 2006, 85 (12-13) :1743-1749
[10]   Synthesis of biodiesel via acid catalysis [J].
Lotero, E ;
Liu, YJ ;
Lopez, DE ;
Suwannakarn, K ;
Bruce, DA ;
Goodwin, JG .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (14) :5353-5363