New heterocyclic systems to afford microsecond green-light isomerisable azo dyes and their use as fast molecular photochromic switches

被引：60

作者：

Garcia-Amoros, Jaume ^{[1
]}

Castro, M. Cidalia R. ^{[2
]}

Coelho, Paulo ^{[3
]}

Raposo, M. Manuela M. ^{[2
]}

Velasco, Dolores ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Organ, Grp Mat Organ, Inst Nanociencia & Nanotecnol IN2UB, E-08028 Barcelona, Spain

[2] Univ Minho, Ctr Quim, P-4710057 Braga, Portugal

[3] Univ Traas Os Montes & Alto Douro, Ctr Quim Vila Real, P-5001801 Vila Real, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 97期

关键词：

TRANS ISOMERIZATION; AZOBENZENE; THIENYLPYRROLE; CONDUCTANCE; ELASTOMER; THIAZOLE;

D O I：

10.1039/c3cc46736h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of benzothiazole as an electron-withdrawing group allows obtaining the fastest thermal isomerisation kinetics reported heretofore for neutral azo dyes (70 mu s at 298 K). These green light activatable molecules are valuable candidates as molecular photo-switches since they tolerate thousands of working cycles with no sign of fatigue.

引用

页码：11427 / 11429

页数：3

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