High-Capacity Sodium Peroxide Based Na-O2 Batteries with Low Charge Overpotential via a Nanostructured Catalytic Cathode

被引：24

作者：

Ma, Lu ^{[1
]}

Zhang, Dongzhou ^{[3
]}

Lei, Yu ^{[4
]}

Yuan, Yifei ^{[2
]}

Wu, Tianpin ^{[1
]}

Lu, Jun ^{[2
]}

Amine, Khalil ^{[2
]}

机构：

[1] Argonne Natl Lab, Xray Sci Div, Lemont, IL 60439 USA

[2] Argonne Natl Lab, Adv Photon Sources, Chem Sci & Engn Div, Lemont, IL 60439 USA

[3] Univ Hawaii Manoa, Partnership Extreme Crystallog, Honolulu, HI 96822 USA

[4] Univ Alabama Huntsville, Dept Chem & Mat Engn, Huntsville, AL 35899 USA

来源：

ACS ENERGY LETTERS | 2018年 / 3卷 / 02期

关键词：

LI-O-2; BATTERIES; AIR BATTERIES; LITHIUM SUPEROXIDE; DISPROPORTIONATION; NANOTUBES; NAO2;

D O I：

10.1021/acsenergylett.7b01143

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The superoxide based Na-O-2 battery has circumvented the issue of large charge overpotential in Li-O-2 batteries; however, the one-electron process leads to limited capacity. Herein, a sodium peroxide based low-overpotential (similar to 0.5 V) Na-O-2 battery with a capacity as high as 7.5 mAh/cm(2) is developed with Pd nanoparticles as catalysts on the cathode.

引用

页码：276 / 277

页数：2

共 14 条

[1] Sodium-oxygen batteries: a new class of metal-air batteries [J].

Das, Shyamal K. ;

Lau, Sampson ;

Archer, Lynden A. .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (32) :12623-12629

[2]

Hartmann P, 2013, NAT MATER, V12, P228, DOI [10.1038/nmat3486, 10.1038/NMAT3486]

[3] Recent progress and perspectives on bi-functional oxygen electrocatalysts for advanced rechargeable metal-air batteries [J].

Lee, Dong Un ;

Xu, Pan ;

Cano, Zachary P. ;

Kashkooli, Ali Ghorbani ;

Park, Moon Gyu ;

Chen, Zhongwei .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (19) :7107-7134

[4] A lithium-oxygen battery based on lithium superoxide [J].

Lu, Jun ;

Lee, Yun Jung ;

Luo, Xiangyi ;

Lau, Kah Chun ;

Asadi, Mohammad ;

Wang, Hsien-Hau ;

Brombosz, Scott ;

Wen, Jianguo ;

Zhai, Dengyun ;

Chen, Zonghai ;

Miller, Dean J. ;

Jeong, Yo Sub ;

Park, Jin-Bum ;

Fang, Zhigang Zak ;

Kumar, Bijandra ;

Salehi-Khojin, Amin ;

Sun, Yang-Kook ;

Curtiss, Larry A. ;

Amine, Khalil .

NATURE, 2016, 529 (7586) :377-+

[5] Aprotic and Aqueous Li-O2 Batteries [J].

Lu, Jun ;

Li, Li ;

Park, Jin-Bum ;

Sun, Yang-Kook ;

Wu, Feng ;

Amine, Khalil .

CHEMICAL REVIEWS, 2014, 114 (11) :5611-5640

[6] A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries [J].

Lu, Jun ;

Lei, Yu ;

Lau, Kah Chun ;

Luo, Xiangyi ;

Du, Peng ;

Wen, Jianguo ;

Assary, Rajeev S. ;

Das, Ujjal ;

Miller, Dean J. ;

Elam, Jeffrey W. ;

Albishri, Hassan M. ;

Abd El-Hady, D. ;

Sun, Yang-Kook ;

Curtiss, Larry A. ;

Amine, Khalil .

NATURE COMMUNICATIONS, 2013, 4

[7] Probing the Reaction Kinetics of the Charge Reactions of Nonaqueous Li-O2 Batteries [J].

Lu, Yi-Chun ;

Shao-Horn, Yang .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (01) :93-99

[8] Rate-Dependent Nucleation and Growth of NaO2 in Na-O2 Batteries [J].

Ortiz-Vitoriano, Nagore ;

Batcho, Thomas P. ;

Kwabi, David G. ;

Han, Binghong ;

Pour, Nir ;

Yao, Koffi Pierre Claver ;

Thompson, Carl V. ;

Shao-Horn, Yang .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (13) :2636-2643

[9] Oxygen Reactions in a Non-Aqueous Li+ Electrolyte [J].

Peng, Zhangquan ;

Freunberger, Stefan A. ;

Hardwick, Laurence J. ;

Chen, Yuhui ;

Giordani, Vincent ;

Barde, Fanny ;

Novak, Petr ;

Graham, Duncan ;

Tarascon, Jean-Marie ;

Bruce, Peter G. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (28) :6351-6355

[10] Self-stacked nitrogen-doped carbon nanotubes as long-life air electrode for sodium-air batteries: Elucidating the evolution of discharge product morphology [J].

Sun, Qian ;

Yadegari, Hossein ;

Banis, Mohammad N. ;

Liu, Jian ;

Xiao, Biwei ;

Wang, Biqiong ;

Lawes, Stephen ;

Li, Xia ;

Li, Ruying ;

Sun, Xueliang .

NANO ENERGY, 2015, 12 :698-708

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