2 MeV electron irradiation effects on bulk and interface of atomic layer deposited high-k gate dielectrics on silicon

被引:9
作者
Garcia, H. [1 ]
Castan, H. [1 ]
Duenas, S. [1 ]
Bailon, L. [1 ]
Campabadal, F. [2 ]
Rafi, J. M. [2 ]
Zabala, M. [2 ]
Beldarrain, O. [2 ]
Ohyama, H. [3 ]
Takakura, K. [3 ]
Tsunoda, I. [3 ]
机构
[1] Univ Valladolid, ETSI Telecomunicac, Dept Elect & Elect, E-47011 Valladolid, Spain
[2] CSIC, Inst Microelect Barcelona IMB CNM, Bellaterra 08193, Spain
[3] Kumamoto Natl Coll Technol, Dept Elect Engn, Kumamoto 8611102, Japan
关键词
High-k dielectrics; Electrical characterization; Irradiation; Hafnium oxide; Aluminum oxide; Atomic layer deposition; RAY-IRRADIATION; OXIDE; AL2O3; HAFNIUM; FILMS;
D O I
10.1016/j.tsf.2013.02.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
2 MeV electron irradiation effects on the electrical properties of Al2O3 and HfO2-based metal-insulator-semiconductor capacitors have been studied. High-k dielectrics were directly grown on silicon by atomic layer deposition. Capacitors were exposed to three different electron irradiation doses of 0.025, 0.25 and 2.5 MGy. Capacitance-voltage, deep-level transient spectroscopy, conductance transients, flat-band voltage transients and current-voltage techniques were used to characterize the defects induced or activated by irradiation on the dielectric bulk and on the interface with silicon substrate. In all cases, positive charge is trapped in the dielectric bulk after irradiation indicating the existence of hole traps in the dielectric. When the samples are exposed to 2 MeV electron beam (e-beam) irradiation, electron-hole pairs are created and holes are then captured by the hole traps. Insulator/semiconductor interface quality slightly improves for low irradiation doses, but it is degraded for high doses. Irradiation always degrades the dielectric layers in terms of gate leakage current: the trapped holes are mobile charge which can contribute to leakage current by hopping from trap to trap. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:482 / 487
页数:6
相关论文
共 22 条
[1]   Stable trapping of electrons and holes in deposited insulating oxides:: Al2O3, ZrO2, and HfO2 [J].
Afanas'ev, VV ;
Stesmans, A .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2518-2526
[2]  
[Anonymous], J APPL PHYS
[3]   Thin high-k dielectric layers deposited by ALD [J].
Campabadal, F. ;
Zabala, M. ;
Rafi, J. M. ;
Acero, M. C. ;
Sanchez, A. ;
Sanchez, J. ;
Sanchez, S. ;
Andreu, R. .
PROCEEDINGS OF THE 2009 SPANISH CONFERENCE ON ELECTRON DEVICES, 2009, :27-30
[4]   CHARGE TRAPPING AND DEVICE DEGRADATION INDUCED BY X-RAY-IRRADIATION IN METAL-OXIDE-SEMICONDUCTOR FIELD-EFFECT TRANSISTORS [J].
CAMPBELL, SA ;
LEE, KH ;
LI, HH ;
NACHMAN, R ;
CERRINA, F .
APPLIED PHYSICS LETTERS, 1993, 63 (12) :1646-1647
[5]   Electrical bias stressing and radiation induced charge trapping in HfO2/SiO2 dielectric stacks [J].
Devine, R. A. B. ;
Busani, T. ;
Quevedo-Lopez, Manuel ;
Alshareef, H. N. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (10)
[6]   Comparative study of flatband voltage transients on high-k dielectric-based metal-insulator-semiconductor capacitors [J].
Duenas, S. ;
Castan, H. ;
Garcia, H. ;
Gomez, A. ;
Bailon, L. ;
Kukli, K. ;
Aarik, J. ;
Ritala, M. ;
Leskela, M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (11) :G241-G246
[7]   Influence of single and double deposition temperatures on the interface quality of atomic layer deposited Al2O3 dielectric thin films on silicon [J].
Dueñas, S ;
Castán, H ;
García, H ;
de Castro, A ;
Bailón, L ;
Kukli, K ;
Aidla, A ;
Aarik, J ;
Mändar, H ;
Uustare, T ;
Lu, J ;
Hårsta, A .
JOURNAL OF APPLIED PHYSICS, 2006, 99 (05)
[8]  
Felix JA, 2006, NATO SCI SER II-MATH, V220, P299
[9]   Radiation-induced charge trapping in thin Al2O3/SiOxNy/Si(100) gate dielectric stacks [J].
Felix, JA ;
Shaneyfelt, MR ;
Fleetwood, DM ;
Meisenheimer, TL ;
Schwank, JR ;
Schrimpf, RD ;
Dodd, PE ;
Gusev, EP ;
D'Emic, C .
IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2003, 50 (06) :1910-1918
[10]   Identification of spatial localization and energetic position of electrically active defects in amorphous high-k dielectrics for advanced devices [J].
Garcia, H. ;
Duenas, S. ;
Castan, H. ;
Bailon, L. ;
Kukli, K. ;
Aarik, J. ;
Ritala, M. ;
Leskelae, M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (2-9) :393-398