An Electrostatic Model for the Unusual Salt Effect on the Stability of Ionic Copolymer Micelles

被引：1
|
作者：
Maeda, Hiroshi [1 ]
机构：
[1] Kyushu Univ, Higashi Ku, Fukuoka 8130011, Japan
来源：
CHEMISTRY LETTERS | 2012年 / 41卷 / 10期
关键词：
SPHERICAL POLYELECTROLYTE BRUSHES; BLOCK-COPOLYMERS; WATER-SURFACE; MICELLIZATION; NANOSTRUCTURE; MONOLAYERS; INTERFACE; LENGTH; LAYER;
D O I：
10.1246/cl.2012.1057
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An interesting observation reported that the critical micelle concentrations of an ionic amphiphilic block copolymer increased with the salt concentration. Numerical solutions of the Poisson-Boltzmann equations for polyelectrolyte brushes have suggested the existence of a region of approximately zero net charges close to the nonpolar core surface. The observed unusual salt effect could be explained if a kind of counter ion condensation is assumed in this region.
引用
收藏
页码：1057 / 1059
页数：3
相关论文
共 50 条
  • [1] Electrostatic contribution to the stability and the synergism of ionic/nonionic mixed micelles in salt solutions
    Maeda, H
    JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (19): : 6043 - 6051
  • [2] Micelles formed by a model ionic graft copolymer
    Gettinger, CL
    Jackson, CL
    Han, CC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 385 - POLY
  • [3] Salt effect in ionic mixed micelles
    Aswal, VK
    CHEMICAL PHYSICS LETTERS, 2003, 371 (3-4) : 371 - 377
  • [4] Dependence of the size of micelles on the salt effect in ionic micellar solutions
    Aswal, VK
    Goyal, PS
    CHEMICAL PHYSICS LETTERS, 2002, 364 (1-2) : 44 - 50
  • [5] Effect of salt on self-assembly in charged block copolymer micelles
    Borisov, OV
    Zhulina, EB
    MACROMOLECULES, 2002, 35 (11) : 4472 - 4480
  • [6] UNUSUAL SELECTIVITY IN SOLUBILIZATION BY BLOCK COPOLYMER MICELLES
    NAGARAJAN, R
    BARRY, M
    RUCKENSTEIN, E
    LANGMUIR, 1986, 2 (02) : 210 - 215
  • [7] ELECTROSTATIC PROPERTIES OF IONIC MICELLES IN AQUEOUS-SOLUTIONS
    FRAHM, J
    DIEKMANN, S
    HAASE, A
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1980, 84 (06): : 566 - 571
  • [8] EFFECT OF AN ATTRACTIVE POTENTIAL ON THE INTERPARTICLE STRUCTURE OF IONIC MICELLES AT HIGH SALT CONCENTRATION
    BENDEDOUCH, D
    CHEN, SH
    JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (04): : 648 - 652
  • [9] Crystal stability of diblock copolymer micelles in solution
    Molina, John Jairo
    Pierleoni, Carlo
    Capone, Barbara
    Hansen, Jean-Pierre
    de Oliveira, Igor Saulo Santos
    MOLECULAR PHYSICS, 2009, 107 (4-6) : 535 - 548
  • [10] Effect of Salt Content on Solubilization of Hydrophobic Polymer by Wormlike Micelles of Ionic Surfactant
    Kwiatkowski, Alexander L.
    Kalinin, Pavel V.
    Philippova, Olga E.
    EURASIAN JOURNAL OF CHEMISTRY, 2024, 114 (02): : 74 - 80
12345