Enantioselective hydrogenation of alpha,beta-unsaturated ketones over palladium on charcoal in the presence of (-)-ephedrine

被引：34
作者：
Thorey, C
Henin, F
Muzart, J
机构：
[1] U. Rech. Rearrangements Thermiques, Univ. de Reims Champagne-Ardenne, 51687 Reims Cédex 2
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 04期
关键词：
D O I：
10.1016/0957-4166(96)00095-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title reaction carried out under an atmosphere of hydrogen led to the corresponding saturated ketones with enantiomeric excesses of up to 36%. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：975 / 976
页数：2
相关论文
共 20 条
[1]  
ABOULHODA J, 1995, TETRAHEDRON-ASYMMETR, V6, P1865
[2]   COMPOUNDS RELATED TO STEROID HORMONES .5. PARTIAL SYNTHESIS OF 21-ACETOXY-17-HYDROXY-16BETA-METHYL-5ALPHA-PREGN-9-ENE-3,20-DIONE [J].
ATTENBURROW, J ;
WILKINSON, PA ;
GRAHAM, W ;
OUGHTON, JF ;
RITCHIE, AC ;
CONNETT, JE .
JOURNAL OF THE CHEMICAL SOCIETY, 1961, (OCT) :4547-+
[3]   CATALYTIC HYDROGENATION OF ALPHA BETA-UNSATURATED KETONES .4. EFFECT OF MEDIUM ON PRODUCT STEREOCHEMISTRY [J].
AUGUSTINE, RL ;
MIGLIORINI, DC ;
FOSCANTE, RE ;
SODANO, CS ;
SISBARRO, MJ .
JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (04) :1075-+
[4]   ENANTIOSELECTIVE SYNTHESIS USING CHIRAL HETEROGENEOUS CATALYSTS [J].
BLASER, HU .
TETRAHEDRON-ASYMMETRY, 1991, 2 (09) :843-866
[5]  
BLASER HU, 1991, HETEROGENEOUS CATALY, V2, P73
[6]   STEROIDAL ANALOGUES OF UNNATURAL CONFIGURATION .2. AUTOXIDATION OF NEUTRAL DELTA17[20]-ENOLS - METHOD OF 17-HYDROXYLATION [J].
ENSLIN, PR .
TETRAHEDRON, 1971, 27 (10) :1909-&
[7]   PHOTOREACTIVITY OF ALPHA-TETRASUBSTITUTED ARYLKETONES - PRODUCTION AND ASYMMETRIC TAUTOMERIZATION OF ARYLENOLS [J].
HENIN, F ;
MBOUNGOUMPASSI, A ;
MUZART, J ;
PETE, JP .
TETRAHEDRON, 1994, 50 (09) :2849-2864
[8]   ENANTIOSELECTIVE PROTONATION OF A SIMPLE ENOL - AMINOALCOHOL-CATALYZED KETONIZATION OF A PHOTOCHEMICALLY PRODUCED 2-METHYLINDEN-3-OL [J].
HENIN, F ;
MUZART, J ;
PETE, JP ;
MBOUNGOUMPASSI, A ;
RAU, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :416-418
[9]   AN ENANTIOSELECTIVE SYNTHESIS OF 3,4-DISUBSTITUTED BUTYROLACTONES [J].
HONDA, T ;
KIMURA, N .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :77-78
[10]   SOME FACILE SYNTHESES OF OPTICALLY-ACTIVE 2-SUBSTITUTED INDANONES, INDANOLS, TETRALONES, AND TETRALOLS VIA THEIR CHROMIUM TRICARBONYL COMPLEXES [J].
JAOUEN, G ;
MEYER, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (16) :4667-4672
12