Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

被引：259
作者：
Boiko, Vladimir N. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 6卷
关键词：
halex-process; perfluoroalkylation; perfluoroalkyl sulfides; SRF-introduction;
D O I：
10.3762/bjoc.6.88
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutical products and, more generally, fine chemicals. A systematic approach is taken depending on the mode of incorporation of the SRF groups and also on the type of reagents used.
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页码：880 / 921
页数：42
相关论文
共 297 条
[1]   Novel synthetic methodologies for fluorination and perfluoroalkylation [J].
Adams, DJ ;
Clark, JH ;
Heath, PA ;
Hansen, LB ;
Sanders, VC ;
Tavener, SJ .
JOURNAL OF FLUORINE CHEMISTRY, 2000, 101 (02) :187-191
[2]   Preparation of trifluoromethyl aryl sulfides using silver(I) trifluoromethanethiolate and an inorganic iodide [J].
Adams, DJ ;
Clark, JH .
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (05) :1456-1460
[3]   Trifluoromethylthiodediazoniation: a simple, efficient route to trifluoromethyl aryl sulfides [J].
Adams, DJ ;
Goddard, A ;
Clark, JH ;
Macquarrie, DJ .
CHEMICAL COMMUNICATIONS, 2000, (11) :987-988
[4]   ARYL FLUOROALKYL SULFIDES .2. PREPARATION BY CONDENSATION OF TRIFLUOROMETHANESULFENYL CHLORIDE WITH AROMATIC SYSTEMS [J].
ANDREADES, S ;
SHEPPARD, WA ;
HARRIS, JF .
JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (04) :898-&
[5]   OUTER-SPHERE AND INNER-SPHERE PROCESSES IN ORGANIC-CHEMISTRY - REACTION OF TRIFLUOROMETHYL BROMIDE WITH ELECTROCHEMICALLY GENERATED AROMATIC ANION RADICALS AND SULFUR-DIOXIDE ANION RADICALS [J].
ANDRIEUX, CP ;
GELIS, L ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) :786-791
[6]   OUTER-SPHERE DISSOCIATIVE ELECTRON-TRANSFER TO ORGANIC-MOLECULES - A SOURCE OF RADICALS OR CARBANIONS - DIRECT AND INDIRECT ELECTROCHEMISTRY OF PERFLUOROALKYL BROMIDES AND IODIDES [J].
ANDRIEUX, CP ;
GELIS, L ;
MEDEBIELLE, M ;
PINSON, J ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3509-3520
[7]  
[Anonymous], [No title captured]
[8]  
Ayerst McKenna and Harrison Inc, 1989, Canada Patent, Patent No. [1,248,127, 1248127]
[9]   THE HETEROLYTIC FISSION OF THE CARBON-IODINE BOND IN TRIFLUOROIODOMETHANE [J].
BANUS, J ;
EMELEUS, HJ ;
HASZELDINE, RN .
JOURNAL OF THE CHEMICAL SOCIETY, 1951, (JAN) :60-64
[10]  
Barbor A. K., 1970, USPEKHI KHIMII FTORA, V3-4, P90
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