Coffee origin discrimination by paper spray mass spectrometry and direct coffee spray analysis

被引:48
作者
Garrett, Rafael [1 ,2 ]
Rezende, Claudia M. [2 ]
Ifa, Demian R. [1 ]
机构
[1] York Univ, Ctr Res Mass Spectrometry, Toronto, ON M3J 1P3, Canada
[2] Univ Fed Rio de Janeiro, Inst Chem, BR-21945970 Rio De Janeiro, RJ, Brazil
基金
加拿大自然科学与工程研究理事会;
关键词
CHLOROGENIC ACIDS; ARABICA L; IONIZATION; GREEN; IDENTIFICATION; QUALITY; BEANS;
D O I
10.1039/c3ay41247d
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Here we explore the application of the ambient ionization technique paper spray mass spectrometry (PS-MS) combined with the multivariate statistical tools principal component analysis and hierarchical cluster analysis as a fast and simple method to discriminate green arabica coffee beans from three different origins in Brazil. PS-MS does not require nebulizing gas or complex protocols for sample preparation and by the analysis of 5 mu L of whole coffee bean extracts it was possible to discriminate the coffee origin. Furthermore, we report the direct analysis of a single coffee bean using a bean slice as the sample and also the substrate for electrospray ionization.
引用
收藏
页码:5944 / 5948
页数:5
相关论文
共 33 条
[1]   Botanical and Geographical Characterization of Green Coffee (Coffea arabica and Coffea canephora): Chemometric Evaluation of Phenolic and Methylxanthine Contents [J].
Alonso-Salces, Rosa M. ;
Serra, Francesca ;
Reniero, Fabiano ;
Heberger, Karoly .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2009, 57 (10) :4224-4235
[2]   Green and Roasted Arabica Coffees Differentiated by Ripeness, Process and Cup Quality via Electrospray Ionization Mass Spectrometry Fingerprinting [J].
Amorim, Ana Carolina L. ;
Hovell, Ana Maria C. ;
Pinto, Angelo C. ;
Eberlin, Marcos N. ;
Arruda, Neusa P. ;
Pereira, Elenilda J. ;
Bizzo, Humberto R. ;
Catharino, Rodrigo R. ;
Morais Filho, Zenildo B. ;
Rezende, Claudia M. .
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2009, 20 (02) :313-321
[3]  
Anzueto F., 2005, ESPRESSO COFFEE SCI, V2nd, P21
[4]   Comparison of the effectiveness of fatty acids, chlorogenic acids, and elements for the chemometric discrimination of coffee (Coffea arabica L.) varieties and growing origins [J].
Bertrand, Benoit ;
Villarreal, Diana ;
Laffargue, Andreina ;
Posada, Huver ;
Lashermes, Philippe ;
Dussert, Stephane .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (06) :2273-2280
[5]  
Bytof G, 2000, J APPL BOT-ANGEW BOT, V74, P131
[6]   Determination of coffee origins by integrated metabolomic approach of combining multiple analytical data [J].
Choi, Moon-Young ;
Choi, Wanseok ;
Park, Jeong Hill ;
Lim, Johan ;
Kwon, Sung Won .
FOOD CHEMISTRY, 2010, 121 (04) :1260-1268
[7]   Hierarchical scheme for LC-MSn identification of chlorogenic acids [J].
Clifford, MN ;
Johnston, KL ;
Knight, S ;
Kuhnert, N .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (10) :2900-2911
[8]   Chemical fingerprint analysis for quality assessment and control of Bansha herbal tea using paper spray mass spectrometry [J].
Deng, Jiewei ;
Yang, Yunyun .
ANALYTICA CHIMICA ACTA, 2013, 785 :82-90
[9]  
Fenn J. B., 2001, US Patent, Patent No. [6, 2 97, 499, 6297499]
[10]   Discrimination of arabica coffee cultivars by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry and chemometrics [J].
Garrett, Rafael ;
Schmidt, Eduardo M. ;
Pereira, Luiz Filipe P. ;
Kitzberger, Cintia S. G. ;
Scholz, Maria Brigida S. ;
Eberlin, Marcos N. ;
Rezende, Claudia M. .
LWT-FOOD SCIENCE AND TECHNOLOGY, 2013, 50 (02) :496-502