Synthesis and Crystal Structure of [Cu2(TTA)4•(4,4′-bpy)]

被引：1
|
作者：
Jiang, Guang-Qi [1 ]
Lu, Yong-Zhong [1 ]
Li, Xian-Ling [1 ]
Wei, Ran-Shi [1 ]
Shao, Lin [1 ]
机构：
[1] Guizhou Univ, Coll Chem & Chem Engn, Guiyang 550025, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 08期
关键词：
Copper(II); 4,4 '-Bipyridine; 2-Thenoyltrifluoracetone; Crystal structure; HYDROTHERMAL SYNTHESIS; COMPLEX; 4,4-BIPYRIDINE; INCLUSION; NETWORK;
D O I：
10.14233/ajchem.2013.14213
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new complex, [Cu-2(TTA)(4)center dot(4,4'-bpy)] (TTA = 2-thenoly-trifluoracentone, bpy = bipyridine) with the molecular formula C42H28N2O8S4F12Cu2 has been synthesized and structurally characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. The crystal belongs to tricline system, P-1 group with unit cell parameters: a = 8.57557(7) angstrom, b = 10.2215(8) angstrom, c = 13.9964(12) angstrom, alpha = 72.548(3)degrees, beta = 85.407(3)degrees, gamma = 56.130(3)degrees. V = 1162.4 (17) angstrom(3), Z = 1, Mr = 1172.04, Dc = 1.6700 (2) g/cm(3), mu = 1.193 mm(-1), F(000) = 588.0, R = 0.0601, wR = 0.1889 for 4044 reflections with I > 2 sigma (I).
引用
收藏
页码：4709 / 4710
页数：2
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