Gel Polymer Electrolytes for Electrochemical Energy Storage

被引：808
作者：
Cheng, Xunliang [1 ,2 ]
Pan, Jian [1 ,2 ]
Zhao, Yang [1 ,2 ]
Liao, Meng [1 ,2 ]
Peng, Huisheng [1 ,2 ]
机构：
[1] Fudan Univ, State Key Lab Mol Engn Polymers, Dept Macromol Sci, Shanghai 200438, Peoples R China
[2] Fudan Univ, Adv Mat Lab, Shanghai 200438, Peoples R China
来源：
ADVANCED ENERGY MATERIALS | 2018年 / 8卷 / 07期
关键词：
batteries; electrochemical; energy storage; functional; gel polymer electrolytes; LITHIUM-ION BATTERIES; SOLID-STATE SUPERCAPACITORS; DOUBLE-LAYER CAPACITOR; COMPOSITE POLYMER; PHASE-INVERSION; MICROPOROUS MEMBRANE; IMPROVED PERFORMANCE; HFP ELECTROLYTE; SELF-PROTECTION; REDOX ADDITIVES;
D O I：
10.1002/aenm.201702184
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
With the booming development of flexible and wearable electronics, their safety issues and operation stabilities have attracted worldwide attentions. Compared with traditional liquid electrolytes, gel polymer electrolytes (GPEs) are preferred due to their higher safety and adaptability to the design of flexible energy storage devices. This review summarizes the recent progress of GPEs with enhanced physicochemical properties and specified functionalities for the application in electrochemical energy storage. Functional GPEs that are capable to achieve unity lithium-ion transference number and offer additional pseudocapacitance to the overall capacitance are carefully discussed. The smart GPEs with self-protection, thermotolerant, and self-healing abilities are particularly highlighted. To close, the future directions and remaining challenges of the GPEs for application in electrochemical energy storages are summarized to provide clues for the following development.
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页数：16
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