Organic semiconductor perylenetetracarboxylic diimide (PTCDI) electrodes for electrocatalytic reduction of oxygen to hydrogen peroxide

被引：32

作者：

Warczak, Magdalena ^{[1
]}

Gryszel, Maciej ^{[1
]}

Jakesova, Marie ^{[1
]}

Derek, Vedran ^{[1
,2
]}

Glowacki, Eric Daniel ^{[1
]}

机构：

[1] Linkopings Univ, Lab Organ Elect, ITN Campus Norrkoping,Bredgatan 34, S-60221 Norrkoping, Sweden

[2] Rudjer Boskovic Inst, Ctr Excellence Adv Mat & Sensing Devices, Zagreb 10000, Croatia

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 16期

关键词：

DISSOLVED-OXYGEN; PIGMENTS; COMPLEX; COLOR; CELL;

D O I：

10.1039/c7cc08471d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen peroxide is one of the most important industrial chemicals and there is great demand for the production of H2O2 usingmore sustainable and environmentally benign methods. We show electrochemical production of H2O2 by the reduction of O-2, enabled by an organic semiconductor catalyst, N,N'-dimethyl perylenetetracarboxylic diimide (PTCDI). We make PTCDI cathodes that are capable of stable and reusable operation in aqueous electrolytes in a pH range of 1-13 with a catalytic figure of merit as high as 26 kg H2O2 per g catalyst per h. These performance and stability open new avenues for organic small molecule semiconductors as electrocatalysts.

引用

页码：1960 / 1963

页数：4

共 23 条

[11] Hydrogen-Bonded Organic Semiconductors as Stable Photoelectrocatalysts for Efficient Hydrogen Peroxide Photosynthesis
Jakesova, Marie
Apaydin, Dogukan Hazar
Sytnyk, Mykhailo
Oppelt, Kerstin
Heiss, Wolfgang
Sariciftci, Niyazi Serdar
Glowacki, Eric Daniel
[J]. ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (29) : 5248 - 5254
[12] CRYSTALLOCHROMY AS A SOLID-STATE EFFECT - CORRELATION OF MOLECULAR-CONFORMATION, CRYSTAL PACKING AND COLOR IN PERYLENE-3,4-9,10-BIS(DICARBOXIMIDE) PIGMENTS
KLEBE, G
GRASER, F
HADICKE, E
BERNDT, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1989, 45 : 69 - 77
[13] Efficient Photocatalytic Production of Hydrogen Peroxide from Water and Dioxygen with Bismuth Vanadate and a Cobalt(II) Chlorin Complex
Mase, Kentaro
Yoneda, Masaki
Yamada, Yusuke
Fukuzumi, Shunichi
[J]. ACS ENERGY LETTERS, 2016, 1 (05): : 913 - 919
[14] Oxygen-induced doping on reduced PEDOT
Mitraka, E.
Jafari, M. J.
Vagin, M.
Liu, X.
Fahlman, M.
Ederth, T.
Berggren, M.
Jonsson, M. P.
Crispin, X.
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (09) : 4404 - 4412
[15] HYDROGEN-PEROXIDE PRODUCTION IN TRICKLE-BED ELECTROCHEMICAL REACTORS
OLOMAN, C
WATKINSON, AP
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1979, 9 (01) : 117 - 123
[16] Electrochemical generation of hydrogen peroxide from dissolved oxygen in acidic solutions
Qiang, ZM
Chang, JH
Huang, CP
[J]. WATER RESEARCH, 2002, 36 (01) : 85 - 94
[17] Integration of organic FETs with organic photodiodes for a large area, flexible, and lightweight sheet image scanners
Someya, T
Kato, Y
Iba, S
Noguchi, Y
Sekitani, T
Kawaguchi, H
Sakurai, T
[J]. IEEE TRANSACTIONS ON ELECTRON DEVICES, 2005, 52 (11) : 2502 - 2511
[18] Aqueous photocathode activity of regioregular poly(3-hexylthiophene)
Suppes, Graeme
Ballard, Edward
Holdcroft, Steven
[J]. POLYMER CHEMISTRY, 2013, 4 (20) : 5345 - 5350
[19] 2-LAYER ORGANIC PHOTOVOLTAIC CELL
TANG, CW
[J]. APPLIED PHYSICS LETTERS, 1986, 48 (02) : 183 - 185
[20] Biscoumarin-containing acenes as stable organic semiconductors for photocatalytic oxygen reduction to hydrogen peroxide
Weclawski, Marek K.
Jakesova, Marie
Charyton, Martyna
Demitri, Nicola
Koszarna, Beata
Oppelt, Kerstin
Sariciftci, Serdar
Gryko, Daniel T.
Glowacki, Eric Daniel
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (39) : 20780 - 20788

← 1 2 3 →