General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and ,α,β-Unsaturated Aldehydes

被引：155

作者：

Fleischer, Steffen ^{[1
]}

Zhou, Shaolin ^{[2
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

[2] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 19期

关键词：

alcohols; hydrogenation; iron; reduction; synthetic methods; ASYMMETRIC TRANSFER HYDROGENATION; BIOMIMETIC TRANSFER HYDROGENATION; TRANSITION-METAL; SELECTIVE HYDROSILYLATION; REDUCTIVE AMINATION; COMPLEXES; LIGANDS; REACTIVITY; TRENDS;

D O I：

10.1002/anie.201301239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β-unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5120 / 5124

页数：5

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