The pyrolysis simulation of five biomass species by hemi-cellulose, cellulose and lignin based on thermogravimetric curves

被引:165
作者
Zhou, Hui [1 ]
Long, YanQiu [1 ]
Meng, AiHong [1 ,2 ]
Li, QingHai [1 ]
Zhang, YanGuo [1 ]
机构
[1] Tsinghua Univ, Dept Thermal Engn, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Sch Environm, Beijing 100084, Peoples R China
关键词
Biomass; Pyrolysis; TGA; Simulation; DYNAMIC PYROLYSIS; HIGH-TEMPERATURE; RAPID PYROLYSIS; KINETIC-MODELS; HEMICELLULOSE; DEGRADATION; COMBUSTION; IMPACT; RICE;
D O I
10.1016/j.tca.2013.04.040
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal behavior of five biomass species was investigated using a thermogravimetric analyzer (TGA). The investigation showed that the hemi-cellulose in fruit vegetable biomass differed from that in wood biomass. The cellulose in different materials except Chinese cabbage presented coincident properties while different lignin varied greatly because of various monomers. The thermogravimetric curve overlap ratio was applied to evaluate the simulation of biomass by hemi-cellulose, cellulose and lignin. The results indicated that biomass pyrolysis characteristics could be well simulated by its components and the results from the overlap ratio were compared with the content derived from chemical separation. The temperature was programmed to divide each phase of biomass pyrolysis to investigate further components ratio in biomass mass loss process. The results suggested that fruit vegetable biomass contained more hemi-cellulose and less lignin than wood biomass, and poplar wood contained the largest amount of cellulose. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:36 / 43
页数:8
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