Preparation of a Nylon-11 Precursor from Renewable Canola Oil

被引：15

作者：

Spiccia, Nicolas Daniel ^{[1
]}

Border, Emily ^{[1
]}

Illesinghe, Jayamini ^{[1
]}

Jackson, William Roy ^{[1
]}

Robinson, Andrea Jane ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

SYNTHESIS-STUTTGART | 2013年 / 45卷 / 12期

基金：

澳大利亚研究理事会;

关键词：

metathesis; hydrogenation; amination; catalysis; polymers; nylon-11; canola; renewable; CROSS-METATHESIS REACTIONS; RAW-MATERIALS; NATURAL OILS; METHOXYCARBONYLATION; ESTERS; FATS;

D O I：

10.1055/s-0033-1338478

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a multi-catalytic sequence to a valuable nylon-11 precursor, methyl 11-aminoundecanoate, which is prepared by a ruthenium-catalysed cross-metathesis and a highly regioselective palladium-catalysed amination-hydrogenation reaction, from canola oil, a renewable, natural vegetable oil feedstock.

引用

页码：1683 / 1688

页数：6

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