Redox, complexation, and substitution reactions in [Cu2B10H10]-2,2′-bipyridylamine-CH3CN system

被引：28

作者：

Avdeeva, V. V. ^{[1
]}

Dziova, A. E. ^{[1
]}

Polyakova, I. N. ^{[1
]}

Goeva, L. V. ^{[1
]}

Malinina, E. A. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 58卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

METALS;

D O I：

10.1134/S003602361306003X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Cu2B10H10] with 2,2'-bipyridylamine (bpa) in acetonitrile was studied. A redox reaction was found to proceed in reaction solution at ambient temperature. Copper coordination compounds with the metal of different oxidation states-[Cu (2) (I) (bpa)(2)B10H10] center dot 2NCCH(3), [Cu (4) (II) (bpa)(4)(OH)(4)][Cu (2) (I) (B10H10)(3)] center dot nNCCH(3), [Cu-II(bpa)(2)(NCCH3)(2)](2-B(10)H(9)bpa)(2) center dot 2H(2)O, [Cu (2) (II) (bpa)(2)(OH)(2)B10H10], and [(Cu (2) (II) (bpa)(2)(CO3)(2)] center dot H2O-were isolated under various reaction conditions. The compounds were characterized by IR spectroscopy, X-ray crystallography, and elemental analysis.

引用

页码：657 / 663

页数：7

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