Transition-Metal-Free Amination of Aryl boronic Acids and Their Derivatives

被引：40

作者：

Coeffard, Vincent ^{[1
]}

Moreau, Xavier ^{[1
]}

Thomassigny, Christine ^{[1
]}

Greck, Christine ^{[1
]}

机构：

[1] Univ Versailles St Quentin En Yvelines, CNRS, UMR 8180, Inst Lavoisier Versailles, F-78035 Versailles, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 22期

关键词：

amination; arenes; boronic acids; density functional calculations; synthetic methods; N BOND FORMATION; C-N; ELECTROPHILIC AMINATION; COUPLING REACTIONS;

D O I：

10.1002/anie.201300382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free rein: Advances in transition-metal-free direct amination of aryl boronic acids and their derivatives have been recently described (see scheme). These reactions are based on the use of hydroxylamine or azide derivatives and offer great potential for further applications. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5684 / 5686

页数：3

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