Polyester networks based upon epoxidized and maleinated natural oils

被引:53
作者
Warth, H
Mulhaupt, R
Hoffmann, B
Lawson, S
机构
[1] UNIV FREIBURG,FREIBURGER MAT FORSCHUNGSZENTRUM,D-79104 FREIBURG,GERMANY
[2] UNIV FREIBURG,INST MAKROMOL CHEM,D-79104 FREIBURG,GERMANY
来源
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1997年 / 249卷
关键词
D O I
10.1002/apmc.1997.052490106
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Novel families of flexible, semiflexible and rigid crosslinked polyesters were prepared from modified natural oils such as soybean, rape-seed and linseed oil. Maleinated oils were used as anhydride-functional curing agents of epoxy resins such as bisphenol-A-diglycidylether and epoxidized natural oils. A new class of unsaturated polyester resins was based upon maleic anhydride, epoxidized natural oils and styrene. The resulting thermosetting polyesters were reinforced with natural fibers such as hemp and flax fibers. The influence of molecular architectures, curing conditions and formulations on thermal, mechanical and morphological properties were investigated.
引用
收藏
页码:79 / 92
页数:14
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