Binuclear heterometallic {M-Ln} pivalate complexes (M = Co, Ni, Cu; Ln = Sm, Gd): synthesis, structure, and thermolysis

被引：9
|
作者：
Orlova, E. V. [1 ]
Goldberg, A. E. [1 ]
Kiskin, M. A. [1 ]
Koroteev, P. S. [1 ]
Emelina, A. L. [2 ]
Bykov, M. A. [2 ]
Aleksandrov, G. G. [1 ]
Dobrokhotova, Zh V. [1 ]
Novotortsev, V. M. [1 ]
Eremenko, I. L. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
heterometallic complexes; cobalt complexes; nickel complexes; lanthanide complexes; X-ray diffraction study; thermolysis; ICTAC KINETICS PROJECT; SOLID-PHASE THERMOLYSIS; COMPUTATIONAL ASPECTS; THERMAL-DECOMPOSITION; TRIMETHYLACETATE COMPLEXES; HETERONUCLEAR COMPLEXES; COORDINATION-COMPOUNDS; MAGNETIC-PROPERTIES; PART; NICKEL(II);
D O I：
10.1007/s11172-011-0343-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Binuclear heterometallic complexes (eta(2)-bpy)CoLn(Piv)(5)(H2O), (eta(2)-bpy)NiLn(Piv)(5)(H2O), and (eta(2)-bpy)CuLn(Piv)(5)(HPiv) (Ln = Sm or Gd, Piv- is the pivalate anion) were synthesized. A comparative study of the structural characteristics and the thermolysis of the resulting compounds was performed.
引用
收藏
页码：2236 / 2250
页数：15
相关论文
共 50 条
  • [1] Binuclear heterometallic {M-Ln} pivalate complexes (M = Co, Ni, Cu; Ln = Sm, Gd): synthesis, structure, and thermolysis
    E. V. Orlova
    A. E. Goldberg
    M. A. Kiskin
    P. S. Koroteev
    A. L. Emelina
    M. A. Bykov
    G. G. Aleksandrov
    Zh. V. Dobrokhotova
    V. M. Novotortsev
    I. L. Eremenko
    Russian Chemical Bulletin, 2011, 60 : 2236 - 2250
  • [2] Di-and tetranuclear heterometallic Cu~Ⅱ -Ln~Ⅲ complexes (Ln=Gd and Dy): Synthesis, structure and magnetic properties
    ZHANG ZeMin
    State Key Laboratory of Optoelectronic Materials and Technologies
    School of Chemistry and Chemical Engineering
    Science China(Chemistry), 2012, 55 (06) : 934 - 941
  • [3] Chemical trend of Ln-M exchange couplings in heterometallic complexes with Ln = Gd, Tb, Dy, Ho, Er and M = Cu, V
    Watanabe, Ryo
    Fujiwara, Kei
    Okazawa, Atsushi
    Tanaka, Go
    Yoshii, Shunsuke
    Nojiri, Hiroyuki
    Ishida, Takayuki
    CHEMICAL COMMUNICATIONS, 2011, 47 (07) : 2110 - 2112
  • [4] Rare-earth transition-metal chalcogenides Ln3MGaS7 (Ln=Nd, Sm, Dy, Er; M=Co, Ni) and Ln3MGaSe7 (Ln=Nd, Sm, Gd, Dy, M=Co; Ln=Nd, Gd, Dy, M=Ni)
    Yin, Wenlong
    Shi, Youguo
    Kang, Bin
    Deng, Jianguo
    Yao, Jiyong
    Wu, Yicheng
    JOURNAL OF SOLID STATE CHEMISTRY, 2014, 213 : 87 - 92
  • [5] Sandwich d/f Heterometallic Complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru)
    Grechi, Cristian
    Carlotto, Silvia
    Guelfi, Massimo
    Samaritani, Simona
    Armelao, Lidia
    Labella, Luca
    MOLECULES, 2024, 29 (16):
  • [6] Synthesis, structure, and reactivity of macro-cyclic heterobimetallic complexes of (Co, Cu), (Co, Ni), (Co, Zn), (Ln, Cu), (Ln, Ni) combinations
    Golchoubian, H
    Waltz, WL
    Quail, JW
    CANADIAN JOURNAL OF CHEMISTRY, 1999, 77 (01) : 37 - 56
  • [7] Synthesis, Structure, and Magnetism of a Family of Heterometallic {Cu2Ln7} and {Cu4Ln12} (Ln = Gd, Tb, and Dy) Complexes: The Gd Analogues Exhibiting a Large Magnetocaloric Effect
    Langley, Stuart K.
    Moubaraki, Boujemaa
    Tomasi, Corrado
    Evangelisti, Marco
    Brechin, Euan K.
    Murray, Keith S.
    INORGANIC CHEMISTRY, 2014, 53 (24) : 13154 - 13161
  • [8] Heteronuclear M(II)-Ln(III) (M = Co, Mn; Ln = La, Pr, Sm, Gd, Dy and Er) coordination polymers: Synthesis, structures and magnetic properties
    Chen, Yanmei
    She, Shixiong
    Zheng, Lina
    Hu, Bin
    Chen, Wenqian
    Xu, Bin
    Chen, Zhou
    Zhou, Fengying
    Li, Yahong
    POLYHEDRON, 2011, 30 (18) : 3010 - 3016
  • [9] Heptanuclear heterometallic Cu5Ln2(Ln = Gd, Tb) complexes: Synthesis, crystal structures, and magnetic properties studies
    Dermitzaki, Despina
    Bistola, Ourania
    Pissas, Michael
    Psycharis, Vassilis
    Sanakis, Yiannis
    Raptopoulou, Catherine P.
    POLYHEDRON, 2018, 150 : 47 - 53
  • [10] Heterometallic cubane-like {M2Ln2} ( M = Ni, Zn; Ln =, Gd, Dy) and {Ni2Y2} aggregates. Synthesis, structures and magnetic properties
    Meng, Zhao-Sha
    Guo, Fu-Sheng
    Liu, Jun-Liang
    Leng, Ji-Dong
    Tong, Ming-Liang
    DALTON TRANSACTIONS, 2012, 41 (08) : 2320 - 2329
12345